MOF晶體薄膜材料的制備及應用

王丹; 王正幫; 王敬鋒; 魯雄剛; 周忠福

doi:10.13374/j.issn2095-9389.2019.03.002

MOF晶體薄膜材料的制備及應用

doi: 10.13374/j.issn2095-9389.2019.03.002

王丹^{1, 2},
王正幫^{2, 3},
王敬鋒⁴,
魯雄剛¹,
周忠福^{1, 5, ,}

1.
上海大學材料科學與工程學院, 上海 200444
2.
卡爾斯魯厄理工學院功能界面所, 卡爾斯魯厄 76344
3.
湖北大學材料科學與工程學院, 武漢 430062
4.
納米技術及應用國家工程研究中心, 上海 200241
5.
亞伯大學物理系, 阿伯里斯特威斯 SY23 3BZ

基金項目:

自然科學基金資助項目 51371112

國家重點基礎研究發展計劃資助項目 2014CB643403

詳細信息

通訊作者:
周忠福, E-mail: z.zhou@shu.edu.cn

中圖分類號: TG142.71
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- 文章訪問數: 2417
- HTML全文瀏覽量: 906
- PDF下載量: 171
- 被引次數: 0
出版歷程
- 收稿日期: 2018-02-13
- 刊出日期: 2019-03-20

Fabrication methods and applications of metal-organic framework thin films

WANG Dan^{1, 2},
WANG Zheng-bang^{2, 3},
WANG Jing-feng⁴,
LU Xiong-gang¹,
ZHOU Zhong-fu^{1, 5
, ,}

1.
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
2.
Institute of Functional Interfaces, Karlsruhe Institute of Technology, Karlsruhe 76344, Germany
3.
School of Materials Science and Engineering, Hubei University, Wuhan 430062, China
4.
National Engineering Research Center for Nanotechnology, Shanghai 200241, China
5.
Department of Physics, Aberystwyth University, Aberystwyth SY23 3BZ, UK

More Information

Corresponding author: ZHOU Zhong-fu E-mail: z.zhou@shu.edu.cn

摘要

摘要: 作為納米技術領域的一種新材料, 金屬-有機骨架(metal-organic framework, MOF)薄膜材料(也稱為SURMOFs)獲得了越來越多研究者的關注.多種合成方法的不斷提出, 為大量合成膜厚度、均勻性、形態、甚至維度均可控的MOF薄膜材料提供了可能性, 并為薄膜材料在更多領域中的應用提供了機會.本文首先介紹了MOF薄膜材料基于液相或真空的各種合成方法及其適用范圍, 其中, 獲得高質量薄膜的最有效方法之一是在基底材料上沉積自組裝單層(SAMs), 進而誘導MOF薄膜的成核及生長.其次, 總結了近年來MOF薄膜材料在分離、催化、傳感等領域的研究進展, 以及為滿足環境可持續發展和對清潔能源的需求, 新發展起來的在光催化、儲能、光伏以及制備各種電子器件領域的應用.在此基礎上, 討論了限制MOF薄膜實際應用的因素(例如薄膜生長機制需要更深入的研究、薄膜質量及薄膜熱電性能等有待進一步提高等), 對相關領域未來的研究方向進行了展望, 以期為MOF薄膜材料進一步的研究發展提供理論參考.
- 金屬-有機框架薄膜 /
- 液相外延法 /
- 催化 /
- 傳感器 /
- 儲能
Abstract: As one of the most promising nanomaterials, metal-organic framework (MOF) thin films (also known as surfacesupported MOF thin films, SURMOFs) have attracted much attention in recent years. The development of various synthetic methods makes it possible to obtain MOF thin films with controlled thickness, uniformity, morphology, and even dimensions, providing tremendous opportunities for more applications. Different synthesis methods of MOF thin films based on liquid phase or vacuum range were first introduced, and one of the most effective ways to fabricate quality thin films was depositing self-assembled monolayers (SAMs) on the primary substrate to further induce the nucleation and growth of MOF thin films. Furthermore, some traditional applications of MOF thin films (e. g. separation, catalysis, sensing) were summarized, as well as some newly-developed applications in photocatalysis, energy storage, photovoltaics, and electronic devices, which meet the demands for environmental sustainability and cleaner energy. Although the future is promising, MOF thin films still face some challenges. Therefore, some key factors those limit the MOF films' practical application were discussed, for example, the unclear growth mechanism of thin films, the poor quality and low film thermoe lectric performance. Based on the review of recent developments, this article will provide references for the future research of MOF thin films.
- metal-organic framework films /
- liquid-phase epitaxy /
- catalysis /
- sensing /
- energy storage

HTML全文

圖 1 熱壓法(HoP) 制備MOF涂層過程的示意圖

Figure 1. Schematic representation of hot-pressing (HoP) method for MOF films fabrication

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圖 2 在SAM官能化基底上生長SURMOF薄膜的方法示意圖. (a) 液相外延法; (b) 浸漬法; (c) 噴涂法

Figure 2. Schematic illustrations of different approaches to fabricate SURMOF thin films on SAM-functionalized substrates: (a) LPE method; (b) dip-ping method; (c) spray method

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圖 3 界面合成法制備MOF薄膜的過程示意圖. (a) 液-液界面法; (b) 氣--液界面法; (c) LB膜技術

Figure 3. Sketch of preparing MOF thin films by interfacial synthesis: (a) liquid-liquid interfacial synthesis; (b) air-liquid interfacial synthesis; (c) Langmuir--Blodgett (LB) technology

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圖 4 自下而上的自組裝法制備MOF薄膜的過程示意圖^[46]

Figure 4. BMA fabrication of NAFS-1 films by combining a layer-bylayer growth technique with the LB method^[46]

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圖 5 基于超薄二維納米片的MOF薄膜制備過程示意圖. (a) 合成二維Co-TCPP (Fe) 納米片; (b) 基于二維納米片的MOF薄膜的組裝過程

Figure 5. Schematic illustrations of preparing ultra-thin 2D nanosheetbased MOF thin films: (a) surfactant-assisted synthesis of 2D CoTCPP (Fe) nanosheets; (b) assembly process of 2D nanosheet-based MOF thin films

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圖 6 電化學方法制備MOF薄膜的示意圖. (a) 陽極沉積; (b) 電泳沉積; (c) 陰極沉積

Figure 6. Schematic illustration of the electrochemical fabrication of MOF thin films: (a) anodic deposition; (b) electrophoretic deposition; (c) ca-thodic deposition

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圖 7 原子層沉積法制備MOF薄膜的過程示意圖

Figure 7. ALD process of MOF thin films fabrication

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圖 8 X射線衍射方法表征二維薄膜材料的示意圖^[60]. (a) 面外模式(out-of-plane) X射線衍射方法獲得的晶面衍射圖譜; (b) 平面模式(in-plane) X射線衍射方法獲得的晶面衍射圖譜; (c) Fe (pz) ₂[Pt (CN) ₄]薄膜

Figure 8. X-ray diffraction characterization of 2D thin films^[60]: (a) patterns obtained by out-of-plane XRD; (b) patterns obtained by in-plane XRD; (c) Fe (pz) ₂[Pt (CN) ₄] (pz: pyrazine) thin films

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圖 9 Ni-MOF/Ni/Ni O/C納米復合膜用于人血清葡萄糖檢測^[87]. (a) 檢測過程示意圖; (b) 不同材料固載的GCE在Na OH (0.1 mol·L^-1) 和葡萄糖(0.4 mmol·L^-1) 混合溶液中的循環伏安(CV) 曲線

Figure 9. Ni-MOF/Ni/Ni O/C nanocomposite-modified GCE applied for glucose detection in human serum sample^[87]: (a) schematic of de-tection process; (b) cyclic voltammetry curves of GCEs immobilized with different materials in Na OH (0.1 mol·L^-1) with 0.4 mmol·L^-1glucose

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圖 10 MOF材料在防腐中的應用^[99]. (a) 制備ZIF-8涂層過程的示意圖; (b) 不同基底材料的直流極化曲線

Figure 10. Application of MOF in anticorrosion^[99]: (a) schematic il-lustration of ZIF-8 coatings synthesis; (b) direct-current (DC) polar-ization curves for different substrates

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