Research progress of core-shell composite absorbing materials

HUANG Wei; WEI Shi-cheng; LIANG Yi; WANG Bo; HUANG Yu-wei; WANG Yu-jiang; XU Bin-shi

doi:10.13374/j.issn2095-9389.2019.05.001

Volume 41 Issue 5

May 2019

Turn off MathJax

Article Contents

Article Navigation > Chinese Journal of Engineering > 2019 > 41(5): 547-556

HUANG Wei, WEI Shi-cheng, LIANG Yi, WANG Bo, HUANG Yu-wei, WANG Yu-jiang, XU Bin-shi. Research progress of core-shell composite absorbing materials[J]. Chinese Journal of Engineering, 2019, 41(5): 547-556. doi: 10.13374/j.issn2095-9389.2019.05.001

Citation:

HUANG Wei, WEI Shi-cheng, LIANG Yi, WANG Bo, HUANG Yu-wei, WANG Yu-jiang, XU Bin-shi. Research progress of core-shell composite absorbing materials[J]. Chinese Journal of Engineering, 2019, 41(5): 547-556. doi: 10.13374/j.issn2095-9389.2019.05.001

Citation:

PDF( 7911 KB)

Research progress of core-shell composite absorbing materials

doi: 10.13374/j.issn2095-9389.2019.05.001

National Key Laboratory for Remanufacturing, Academy of Army Armored Forces, Beijing 100072, China

More Information

Corresponding author: WANG Yu-jiang, E-mail: hitwyj@126.com
Received Date: 2018-11-21
Publish Date: 2019-05-01

Abstract

Abstract

With the rapid development of anti-stealth technology and the iterative renewal of firepower destruction weapons, the battlefield survivability of modern weapons and equipment has been severely tested. In the modern warfare of over-the-horizon, radar detection technology is currently the most widely used method; therefore, reducing the radar echo signal is the most important factor to improve the stealth ability of weapon equipment. Generally, stealth technology is divided into structural stealth and material stealth. Reasonable shape structure design can reduce the radar cross section (RCS) value of a weapon equipment. However, due to the high cost of shape structure and the easy reduction of the comprehensive performance of equipment, there are many limitations in application. Because the stealth technology of materials is relatively simple and the design difficulty is relatively low, the research and application of stealth materials are popular and have been well explored. Although the traditional absorbing materials have the advantages of low cost, good flexibility, and easy processing, they also have the defects of high density, narrow working frequency band, and limited strength. Core-shell microwave absorber is a composite multiphase structure with a spherical particle as the core and one or more layers of heterogeneous materials coated on the outer surface. Because of its unique structure and excellent performance, it is a promising material to solve the existing problems. On the basis of reviewing the working principle of microwave absorbing materials, the advantages of core-shell structure materials in the field of microwave absorbing were discussed. This paper mainly introduced the research progress of different types of core-shell structure microwave absorbing materials explored in recent years as well as summarized and commented on their preparation methods, structure, and microwave absorbing properties; these materials are mainly based on ferrite, magnetic metal powder and its oxide, ceramic, conductive polymer, and carbon series materials. Finally, the development trend of core-shell structure mircrowave absorbing materials was predicted, including multi-layer core-shell structure, yolk-shell stucture and special structure combined with other structures, whisch can provide reference for futher study of core-shell shtucture composite absorbing materials.
- core-shell,
- microwave absorption,
- structure,
- composite,
- property

FullText(HTML)

References(56)

References

[1]	徐劍盛, 周萬城, 羅發, 等. 雷達波隱身技術及雷達吸波材料研究進展. 材料導報, 2014, 28(5): 46 https://www.cnki.com.cn/Article/CJFDTOTAL-CLDB201409011.htm Xu J S, Zhou W C, Luo F, et al. Research progress on radar stealth technique and radar absorbing materials. Mater Rev, 2014, 28(5): 46 https://www.cnki.com.cn/Article/CJFDTOTAL-CLDB201409011.htm
[2]	Liu Z H, Ban G D, Jiang Z Q, et al. Absorbing properties of nickalloy/iron package mica powder composite absorbing materials. J Comput Theor Nanosci, 2017, 14(4): 1794 doi: 10.1166/jctn.2017.6507
[3]	王海濱, 劉樹信, 霍冀川, 等. 無機吸波材料研究進展. 硅酸鹽通報, 2008, 27(4): 754 https://www.cnki.com.cn/Article/CJFDTOTAL-GSYT200804023.htm Wang H B, Liu S X, Huo J C, et al. Progress on inorganic wave-absorbing materials. Bull Chin Ceram Soc, 2008, 27(4): 754 https://www.cnki.com.cn/Article/CJFDTOTAL-GSYT200804023.htm
[4]	胡小賽, 沈勇, 王黎明, 等. 吸波材料研究新進展. 炭素技術, 2016, 35(2): 11 https://www.cnki.com.cn/Article/CJFDTOTAL-TSJS201602004.htm Hu X S, Shen Y, Wang L M, et al. Research progress of novel microwave absorbing materials. Carbon Tech, 2016, 35(2): 11 https://www.cnki.com.cn/Article/CJFDTOTAL-TSJS201602004.htm
[5]	Tian C H, Du Y C, Xu P, et al. Constructing uniform core-shell PPy@ PANI composites with tunable shell thickness toward enhancement in microwave absorption. ACS Appl Mater Interfaces, 2015, 7(36): 20090 doi: 10.1021/acsami.5b05259
[6]	Zhou M, Zhang X, Wang L, et al. Enhanced microwave absorption performance of hollow α-MnO₂ nanourchins. J Nanosci Nanotechnol, 2013, 13(2): 904 doi: 10.1166/jnn.2013.5958
[7]	Liu Q H, Xu X H, Xia W X, et al. Dependency of magnetic microwave absorption on surface architecture of Co₂₀Ni₈₀ hierarchical structures studied by electron holography. Nanoscale, 2015, 7(5): 1736 doi: 10.1039/C4NR05547K
[8]	Yuan K P, Che R C, Cao Q, et al. Designed fabrication and characterization of three-dimensionally ordered arrays of core-shell magnetic mesoporous carbon microspheres. ACS Appl Mater Interfaces, 2015, 7(9): 5312 doi: 10.1021/am508683p
[9]	You W B, She W, Liu Z W, et al. High-temperature annealing of an iron microplate with excellent microwave absorption performance and its direct micromagnetic analysis by electron holography and Lorentz microscopy. J Mater Chem C, 2017, 5(24): 6047 doi: 10.1039/C7TC01544E
[10]	Duan W Y, Yin X W, Li Q, et al. A review of absorption properties in silicon-based polymer derived ceramics. J Eur Ceram Soc, 2016, 36(15): 3681 doi: 10.1016/j.jeurceramsoc.2016.02.002
[11]	Qin F, Brosseau C. A review and analysis of microwave absorption in polymer composites filled with carbonaceous particles. J Appl Phys, 2012, 111(6): 061301 doi: 10.1063/1.3688435
[12]	Ding D, Wang Y, Li X D, et al. Rational design of core-shell Co@C microspheres for high-performance microwave absorption. Carbon, 2017, 111: 722 doi: 10.1016/j.carbon.2016.10.059
[13]	Zhou C, Geng S, Xu X W, et al. Lightweight hollow carbon nanospheres with tunable sizes towards enhancement in microwave absorption. Carbon, 2016, 108: 234 doi: 10.1016/j.carbon.2016.07.015
[14]	Song W L, Zhang K L, Chen M J, et al. A universal permittivity-attenuation evaluation diagram for accelerating design of dielectric-based microwave absorption materials: A case of graphene-based composites. Carbon, 2017, 118: 86 doi: 10.1016/j.carbon.2017.03.016
[15]	Chylekt P. Light scattering by small particles in an absorbing medium. J Opt Soc Am, 1977, 67(4): 561 doi: 10.1364/JOSA.67.000561
[16]	Jánossy L. Classical and wave mechanical theory of Rayleigh scattering. Acta Phys Academiae Scientiarum Hungaricae, 1976, 41(1): 41 doi: 10.1007/BF03157429
[17]	Wagner P E. A constant-angle Mie scattering method (CAMS) for investigation of particle formation processes. J Colloid Interface Sci, 1985, 105(2): 456 doi: 10.1016/0021-9797(85)90319-4
[18]	段濤, 楊玉山, 彭同江, 等. 核殼型納米復合材料的研究進展. 材料導報, 2009, 23(2): 19 https://www.cnki.com.cn/Article/CJFDTOTAL-CLDB200903006.htm Duan T, Yang Y S, Peng T J, et al. Review of progress in core-shell structural nanocomposite material. Mater Rev, 2009, 23(2): 19 https://www.cnki.com.cn/Article/CJFDTOTAL-CLDB200903006.htm
[19]	劉冶, 李竹影, 俞翔, 等. 形狀任意的超材料電磁隱身波長變換器的設計. 裝備環境工程, 2016, 13(1): 98 https://www.cnki.com.cn/Article/CJFDTOTAL-JSCX201601019.htm Liu Y, Li Z Y, Yu X, et al. Design of metamaterial electromagnetic invisible wavelength transformer with arbitrary shape. Equip Environ Eng, 2016, 13(1): 98 https://www.cnki.com.cn/Article/CJFDTOTAL-JSCX201601019.htm
[20]	劉冶, 李竹影, 趙林, 等. 一種無奇異參數橢圓柱形電磁隱身斗篷的設計基礎理論. 裝備環境工程, 2015, 12(1): 6 https://www.cnki.com.cn/Article/CJFDTOTAL-JSCX201501002.htm Liu Y, Li Z Y, Zhao L, et al. A design fundamental theory of elliptic cylindrical invisible cloak with non-singular electromagnetic tensors. Equip Environ Eng, 2015, 12(1): 6 https://www.cnki.com.cn/Article/CJFDTOTAL-JSCX201501002.htm
[21]	Xu J, He F, Gai S L, et al. Nitrogen-enriched, double-shelled carbon/layered double hydroxide hollow microspheres for excellent electrochemical performance. Nanoscale, 2014, 6(18): 10887 doi: 10.1039/C4NR02756F
[22]	Tian C H, Du Y C, Cui C S, et al. Synthesis and microwave absorption enhancement of yolk-shell Fe₃O₄@C microspheres. J Mater Sci, 2017, 52(11): 6349 doi: 10.1007/s10853-017-0866-3
[23]	Ren F J, Yu H J, Wang L, et al. Current progress on the modification of carbon nanotubes and their application in electromagnetic wave absorption. RSC Adv, 2014, 4(28): 14419 doi: 10.1039/c3ra46989a
[24]	Quan B, Liang X H, Ji G B, et al. Dielectric polarization in electromagnetic wave absorption: review and perspective. J Alloys Compd, 2017, 728: 1065 doi: 10.1016/j.jallcom.2017.09.082
[25]	She W, Bi H, Wen Z W, et al. Tunable microwave absorption frequency by aspect ratio of hollow polydopamine@ α-MnO₂ microspindles studied by electron holography. ACS Appl Mater Interfaces, 2016, 8(15): 9782 doi: 10.1021/acsami.6b00978
[26]	Liu X X, Wu Y P, Wu C, et al. Study on permittivity of composites with core-shell particle. Phys B Condens Matter, 2010, 405(8): 2014 doi: 10.1016/j.physb.2010.01.093
[27]	曲兆明, 王慶國, 秦思良, 等. 核殼粒子復合材料的等效磁導率. 材料科學與工藝, 2012, 20(3): 36 https://www.cnki.com.cn/Article/CJFDTOTAL-CLKG201203008.htm Qu Z M, Wang Q G, Qin S L, et al. Effective permeability of composites with core-shell particles. Mater Sci Technol, 2012, 20(3): 36 https://www.cnki.com.cn/Article/CJFDTOTAL-CLKG201203008.htm
[28]	Bergheul S, Otmane F, Azzaz M. Structural and microwave absorption properties of nanostructured Fe-Co alloys. Adv Powder Technol, 2012, 23(5): 580 doi: 10.1016/j.apt.2011.06.004
[29]	Lee C C, Cheng Y Y, Chang H Y, et al. Synthesis and electromagnetic wave absorption property of Ni-Ag alloy nanoparticles. J Alloys Compd, 2009, 480(2): 674 doi: 10.1016/j.jallcom.2009.02.017
[30]	哈日巴拉, 付烏有, 楊海濱, 等. Fe₃O₄/Ni復合納米顆粒的制備及其微波吸收特性. 復合材料學報, 2008, 25(5): 14 doi: 10.3321/j.issn:1000-3851.2008.05.003 Hari B, Fu W Y, Yang H B, et al. Preparation and properties of Fe₃O₄/Ni nanoparticles. Acta Mater Compos Sin, 2008, 25(5): 14 doi: 10.3321/j.issn:1000-3851.2008.05.003
[31]	Drmota A, Koselj J, Drofenik M, et al. Electromagnetic wave absorption of polymeric nanocomposites based on ferrite with a spinel and hexagonal crystal structure. J Magn Magn Mater, 2012, 324(6): 1225 doi: 10.1016/j.jmmm.2011.11.015
[32]	俞梁, 王建江, 許寶才, 等. Co-Zn摻雜的W型鋇鐵氧體空心陶瓷微珠吸波材料的制備與性能研究. 人工晶體學報, 2015, 44(9): 2490 doi: 10.3969/j.issn.1000-985X.2015.09.031 Yu L, Wang J J, Xu B C, et al. Study on the preparation and properties of Co-Zn doped W-type barium ferrite hollow ceramic microsphere absorbing materials. J Synth Cryst, 2015, 44(9): 2490 doi: 10.3969/j.issn.1000-985X.2015.09.031
[33]	Wang G Q, Chang Y F, Wang L F, et al. Synthesis, characterization and microwave absorption properties of Fe₃O₄/Co core/shell-type nanoparticles. Adv Powder Technol, 2012, 23(6): 861 doi: 10.1016/j.apt.2011.12.003
[34]	王曉磊, 包秀坤, 關銀燕, 等. C/Co核殼亞微米復合物的吸波性能. 材料研究學報, 2017, 31(4): 241 https://www.cnki.com.cn/Article/CJFDTOTAL-CYJB201704001.htm Wang X L, Bao X K, Guan Y Y, et al. Microwave absorption properties of submicro-composites of core-shell C/Co. Chin J Mater Res, 2017, 31(4): 241 https://www.cnki.com.cn/Article/CJFDTOTAL-CYJB201704001.htm
[35]	Yuan J, Yang H J, Hou Z L, et al. Ni-decorated SiC powders: Enhanced high-temperature dielectric properties and microwave absorption performance. Powder Technol, 2013, 237: 309 doi: 10.1016/j.powtec.2012.12.020
[36]	Wang B C, Zhang J L, Wang T, et al. Synthesis and enhanced microwave absorption properties of Ni@Ni₂O₃ core-shell particles. J Alloys Compd, 2013, 567: 21 doi: 10.1016/j.jallcom.2013.03.028
[37]	Liu T, Pang Y, Zhu M, et al. Microporous Co@CoO nanoparticles with superior microwave absorption properties. Nanoscale, 2014, 6(4): 2447 doi: 10.1039/c3nr05238a
[38]	朱云斌, 卿玉長, 賈舒, 等. SiO₂包覆羰基鐵的微波吸收性能研究. 材料導報, 2010, 24(1): 9 https://www.cnki.com.cn/Article/CJFDTOTAL-CLDB201002006.htm Zhu Y B, Qing Y C, Jia S, et al. Microwave absorbing properties of SiO₂ coated carbonyl iron particles. Mater Rev, 2010, 24(1): 9 https://www.cnki.com.cn/Article/CJFDTOTAL-CLDB201002006.htm
[39]	Qiao M T, Lei X F, Ma Y, et al. Dependency of tunable microwave absorption performance on morphology-controlled hierarchical shells for core-shell Fe₃O₄ @MnO₂ composite microspheres. Chem Eng J, 2016, 304: 552 doi: 10.1016/j.cej.2016.06.094
[40]	Liu J W, Che R C, Chen H J, et al. Microwave absorption enhancement of multifunctional composite microspheres with spinel Fe₃O₄ cores and anatase TiO₂ shells. Small, 2012, 8(8): 1214 doi: 10.1002/smll.201102245
[41]	張捷, 劉偉, 張婷, 等. 導電聚合物基復合吸波材料的研究進展. 微納電子技術, 2018(2): 91 https://www.cnki.com.cn/Article/CJFDTOTAL-BDTQ201802003.htm Zhang J, Liu W, Zhang T, et al. Research progress of conductive polymer composites for microwave absorption. Micronanoelectron Technol, 2018(2): 91 https://www.cnki.com.cn/Article/CJFDTOTAL-BDTQ201802003.htm
[42]	Wang Y, Wang W, Zhu M F, et al. Electromagnetic wave absorption polyimide fabric prepared by coating with core-shell NiFe₂O₄@PANI nanoparticles. RSC Adv, 2017, 7(68): 42891 doi: 10.1039/C7RA08002F
[43]	景紅霞, 李巧玲, 葉云, 等. 羰基鐵-聚苯胺復合吸波材料的制備及性能. 功能高分子學報, 2012, 25(4): 393 https://www.cnki.com.cn/Article/CJFDTOTAL-GNGF201204012.htm Jing H X, Li Q L, Ye Y, et al. Synthesis and properties of carbonyl iron-polyaniline microwave absorption composites. J Funct Polym, 2012, 25(4): 393 https://www.cnki.com.cn/Article/CJFDTOTAL-GNGF201204012.htm
[44]	Yan L L, Wang X X, Zhao S C, et al. Highly efficient microwave absorption of magnetic nanospindle-conductive polymer hybrids by molecular layer deposition. ACS Appl Mater Interfaces, 2017, 9(12): 11116 doi: 10.1021/acsami.6b16864
[45]	王雯, 王成國, 郭宇, 等. 新型碳基復合吸波材料的制備及性能研究. 航空材料學報, 2012, 32(1): 63 doi: 10.3969/j.issn.1005-5053.2012.1.013 Wang W, Wang C G, Guo Y, et al. Preparation and electromagnetic characteristic of novel carbon based composites. J Aeronautical Mater, 2012, 32(1): 63 doi: 10.3969/j.issn.1005-5053.2012.1.013
[46]	Du Y C, Liu W W, Qiang R, et al. Shell thickness-dependent microwave absorption of core-shell Fe₃O₄@C composites. ACS Appl Mater Interfaces, 2014, 6(15): 12997 doi: 10.1021/am502910d
[47]	Wan G P, Yu L, Peng X G, et al. Preparation and microwave absorption properties of uniform TiO₂@C core-shell nanocrystals. RSC Adv, 2015, 5(94): 77443 doi: 10.1039/C5RA14344F
[48]	卓絕, 黃昊, 丁昂. 直流電弧法制備SiC@C核殼型納米粒子及吸波性能研究. 兵器材料科學與工程, 2016, 39(6): 78 https://www.cnki.com.cn/Article/CJFDTOTAL-BCKG201606022.htm Zhuo J, Huang H, Ding A. Microwave absorbing properties of SiC@C core/shell nanoparticles prepared by arc discharge method. Ordnance Mater Sci Eng, 2016, 39(6): 78 https://www.cnki.com.cn/Article/CJFDTOTAL-BCKG201606022.htm
[49]	刁金香, 王惠. 乙醇裂解制備碳納米管及其生長機理研究. 硅酸鹽通報, 2018, 37(1): 92 https://www.cnki.com.cn/Article/CJFDTOTAL-GSYT201801015.htm Diao J X, Wang H. Synthesis of carbon nanotubes by decomposition of ethanol and its growth mechanism. Bull Chin Ceramic Soc, 2018, 37(1): 92 https://www.cnki.com.cn/Article/CJFDTOTAL-GSYT201801015.htm
[50]	Zhang S L, Qi Z W, Zhao Y, et al. Core/shell structured composites of hollow spherical CoFe₂O₄ and CNTs as absorbing materials. J Alloys Compd, 2017, 694: 309 doi: 10.1016/j.jallcom.2016.09.324
[51]	Wang Y, Zhang W Z, Luo C Y, et al. Fabrication and high-performance microwave absorption of Ni@SnO₂@PPy core-shell composite. Synth Met, 2016, 220: 347 doi: 10.1016/j.synthmet.2016.07.005
[52]	Yu M, Liang C Y, Liu M M, et al. Yolk-shell Fe₃O₄@ZrO₂ prepared by a tunable polymer surfactant assisted sol-gel method for high temperature stable microwave absorption. J Mater Chem C, 2014, 2(35): 7275 doi: 10.1039/C4TC01285B
[53]	Liu J W, Xu J J, Che R C, et al. Hierarchical Fe₃O₄@TiO₂ yolk-shell microspheres with enhanced microwave-absorption properties. Chem Eur J, 2013, 19(21): 6746 doi: 10.1002/chem.201203557
[54]	Zhao B, Guo X Q, Zhao W Y, et al. Facile synthesis of yolk-shell Ni@ void@ SnO₂ (Ni₃Sn₂) ternary composites via galvanic replacement/Kirkendall effect and their enhanced microwave absorption properties. Nano Res, 2017, 10(1): 331 doi: 10.1007/s12274-016-1295-3
[55]	Liu J W, Cheng J, Che R C, et al. Double-shelled yolk-shell microspheres with Fe₃O₄ cores and SnO₂ double shells as high-performance microwave absorbers. J Phys Chem C, 2013, 117(1): 489 doi: 10.1021/jp310898z
[56]	Peng Z, Jiang W, Wang Y P, et al. Synthesis and microwave absorption properties of Fe₃O₄@BaTiO₃/reduced graphene oxide nanocomposites. J Mater Sci Mater Electron, 2016, 27(2): 1304 doi: 10.1007/s10854-015-3890-6