Comparison on the solid-state desilication kinetics of silicon manganese powder by microwave heating and conventional heating

MA Lei-lei; LIAN Fang; ZHANG Fan; DING Peng-chong; LIU Da-liang; CHEN Yan-bin

doi:10.13374/j.issn2095-9389.2017.02.001

Volume 39 Issue 2

Feb. 2017

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Article Navigation > Chinese Journal of Engineering > 2017 > 39(2): 167-174

MA Lei-lei, LIAN Fang, ZHANG Fan, DING Peng-chong, LIU Da-liang, CHEN Yan-bin. Comparison on the solid-state desilication kinetics of silicon manganese powder by microwave heating and conventional heating[J]. Chinese Journal of Engineering, 2017, 39(2): 167-174. doi: 10.13374/j.issn2095-9389.2017.02.001

Citation:

MA Lei-lei, LIAN Fang, ZHANG Fan, DING Peng-chong, LIU Da-liang, CHEN Yan-bin. Comparison on the solid-state desilication kinetics of silicon manganese powder by microwave heating and conventional heating[J]. Chinese Journal of Engineering, 2017, 39(2): 167-174. doi: 10.13374/j.issn2095-9389.2017.02.001

Citation:

MA Lei-lei, LIAN Fang, ZHANG Fan, DING Peng-chong, LIU Da-liang, CHEN Yan-bin. Comparison on the solid-state desilication kinetics of silicon manganese powder by microwave heating and conventional heating[J]. Chinese Journal of Engineering, 2017, 39(2): 167-174. doi: 10.13374/j.issn2095-9389.2017.02.001

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Comparison on the solid-state desilication kinetics of silicon manganese powder by microwave heating and conventional heating

doi: 10.13374/j.issn2095-9389.2017.02.001

1) School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
2) Jiangsu Easpring Material Technology Co., Ltd., Haimen 226100, China

Received Date: 2016-04-25

Abstract

Abstract

Layered Mn-based series Li[Li_x(MnM)_1-x]O₂ (M=Ni, Co, Cr, …) due to its much higher capacity is one of the very promising candidates of cathodes, which has become a research hotspot recently and attracted more and more attention. Especially, with the aid of advanced characterization techniques including in-situ analysis, studies on the complex structure and high-capacity delivering mechanism of the series have achieved significant progress. In the paper, the structural characterization and charge-discharge behavior of the high-energy density layered cathode were briefly introduced. Study progresses on the voltage degradation, interface/surface variation during cycling and performance improvements of Li[Li_x(MnM)_1-x]O₂ were reviewed in detail particularly in view of its exiting issues. Furthermore, the challenges and prospects in the high-energy density layered cathode materials were also discussed herein.
- lithium ion batteries,
- layered materials,
- high energy density,
- voltage fading,
- interface

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References(44)

References

[1]	Lu Z H, MacNeil D D, Dahn J R. Layered cathode materials Li[Ni_xLi_(1/3-2x/3)Mn_(2/3-x/3)]O₂ for lithium-ion batteries. Electrochem Solid State Lett, 2001, 4(11):A191
[2]	Shen C H, Huang L, Lin Z, et al. Kinetics and structural changes of Li-rich layered oxide 0.5Li₂MnO₃·0.5LiNi_0.292Co_0.375-Mn_0.333O₂ material investigated by a novel technique combining in situ XRD and a multipotential step. ACS Appl Mater Interfaces, 2014, 6(15):13271
[3]	Lin C K, Piao Y, Kan Y C, et al. Probing thermally induced decomposition of delithiated Li_1.2-xNi_0.15Mn_0.55Co_0.1O₂ by in-situ high energy X-ray diffraction. ACS Appl Mater Interfaces, 2014, 6(15):12692
[4]	Yu X Q, Lyu Y C, Gu L, et al. Understanding the rate capability of high-energy-density Li-rich layered Li_1.2Ni_0.15Co_0.1Mn_0.55-O₂ cathode materials. Adv Energy Mater, 2014, 4(5):1
[5]	Shen C H, Wang Q, Fu F, et al. Facile synthesis of the Li-rich layered oxide Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ with superior lithium storage performance and new insights into structural transformation of the layered oxide material during charge-discharge cycle:in situ XRD characterization. ACS Appl Mater Interfaces, 2014, 6(8):5516
[6]	Hy S, Felix F, Rick J, et al. Direct in situ observation of Li₂O evolution on Li-rich high-capacity cathode material, Li[Ni_xLi_(1-2x)/3Mn_(2-x)/3]O₂(0 ≤ x ≤ 0.5). J Am Chem Soc, 2014, 136(3):999
[7]	Yang F F, Liu Y J, Martha S K, et al. Nanoscale morphological and chemical changes of high voltage lithium-manganese rich NMC composite cathodes with cycling. Nano Lett, 2014, 14(8):4334
[8]	Yu H J, Zhou H S. High-energy cathode materials (Li₂MnO₃-LiMO₂) for lithium-ion batteries. J Phys Chem Lett, 2013, 4(8):1268
[9]	Jarvis K A, Deng Z Q, Allard L F, et al. Atomic structure of a lithium-rich layered oxide material for lithium-ion batteries:evidence of a solid solution. Chem Mater, 2011, 23(16):3614
[11]	Zheng J M, Gu M, Genc A, et al. Mitigating voltage fade in cathode materials by improving the atomic level uniformity of elemental distribution. Nano Lett, 2014, 14(5):2628
[12]	Koga H, Croguennec L, Mannessiez P, et al. Li_1.20Mn_0.54-Co_0.13Ni_0.13O₂ with different particle sizes as attractive positive electrode materials for lithium-ion batteries:insights into their structure. J Phys Chem C, 2012, 116(25):13497
[13]	Long B R, Croy J R, Dogan F, et al. Effect of cooling rates on phase separation in 0.5Li₂MnO₃·0.5LiCoO₂ electrode materials for Li-ion batteries. Chem Mater, 2014, 26(11):3565
[14]	Yu H J, Ishikawa R, So Y G, et al. Direct atomic-resolution observation of two phases in the Li_1.2Mn_0.567Ni_0.166Co_0.067O₂ cathode material for lithium-ion batteries. Angew Chem Int Ed, 2013, 52(23):5969
[15]	Yoon W S, Kim N, Yang X Q, et al. ⁶Li MAS NMR and in situ X-ray studies of lithium nickel manganese oxides. J Power Sources, 2003, 119-121:649
[16]	Bareño J, Lei C H, Wen J G, et al. Local structure of layered oxide electrode materials for lithium-ion batteries. Adv Mater, 2010, 22(10):1122
[17]	Ohzuku T, Nagayama M, Tsuji K, et al. High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries:toward rechargeable capacity more than 300 mA h g^-1. J Mater Chem, 2011, 21:10179
[18]	Johnson C S, Kim J S, Lefief C, et al. The significance of the Li₂MnO₃ component in ‘composite’ xLi₂MnO₃·(1-x) LiMn_0.5Ni_0.5O₂ electrodes. Electrochem Commun, 2004, 6(10):1085
[19]	Lu Z H, Dahn J R. Understanding the anomalous capacity of Li/Li[Ni_xLi_(1/3-2x/3)Mn_(2/3-x/3)]O₂ cells using in situ X-ray diffraction and electrochemical studies. J Electrochem Soc, 2002, 149(7):A815
[20]	Cao T T, Shi C S, Zhao N Q, et al. Understanding the electrochemical properties of Li-rich cathode materials from first-principles calculations. J Phys Chem C, 2015, 119(52):28749
[21]	Armstrong A R, Holzapfel M, NovaȂk P, et al. Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni_0.2Li _0.2Mn_0.6]O₂. J Am Chem Soc, 2006, 128(26):8694
[22]	Yabuuchi N, Yoshii K, Myung S T, et al. Detailed studies of a high-capacity electrode material for rechargeable batteries, Li₂MnO₃-LiCo_1/3Ni_1/3Mn_1/3O₂. J Am Chem Soc, 2011, 133(12):4404
[23]	Song B H, Day S J, Sui T, et al. Mitigated phase transition during first cycle of a Li-rich layered cathode studied by in operando synchrotron X-ray powder diffraction. Phys Chem Chem Phys, 2016, 18(6):4745
[24]	Mohanty D, Li J L, Abraham D P, et al. Unraveling the voltage-fade mechanism in high-energy-density lithium-ion batteries:origin of the tetrahedral cations for spinel conversion. Chem Mater, 2014, 26(21):6272
[25]	Croy J R, Gallagher K G, Balasubramanian M, et al. Quantifying hysteresis and voltage fade in xLi₂MnO₃·(1-x) LiMn_0.5Ni_0.5O₂ electrodes as a function of Li₂MnO₃ content. J Electrochem Soc, 2013, 161(3):A318
[26]	Bettge M, Li Y, Gallagher K, et al. Voltage fade of layered oxides:its measurement and impact on energy density. J Electrochem Soc, 2013, 160(11):A2046
[27]	Gallagher K G, Croy J R, Balasubramanian M, et al. Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes. Electrochem Commun, 2013, 33:96
[28]	Zheng J M, Xu P H, Gu M, et al. Structural and chemical evolution of Li- and Mn-rich layered cathode material. Chem Mater, 2015, 27(4):1381
[29]	Yan P F, Nie A M, Zheng J M, et al. Evolution of lattice structure and chemical composition of the surface reconstruction layer in Li_1.2Ni_0.2Mn_0.6O₂ cathode material for lithium ion batteries. Nano Lett, 2015, 15(1):514
[30]	Hong J, Lim H D, Lee M, et al. Critical role of oxygen evolved from layered Li-excess metal oxides in lithium rechargeable batteries. Chem Mater, 2012, 24(14):2692
[31]	Castel E, Berg E J, El Kazzi M E, et al. Differential electrochemical mass spectrometry study of the interface of xLi₂MnO₃·(1-x) LiMO₂(M=Ni, Co, and Mn) material as a positive electrode in Li-ion batteries. Chem Mater, 2014, 26(17):5051
[32]	Lee D J, Im D M, Ryu Y G, et al. Phosphorus derivatives as electrolyte additives for lithium-ion battery:The removal of O₂ generated from lithium-rich layered oxide cathode. J Power Sources, 2013, 243:831
[33]	Wang Q Y, Liu J, Murugan A V, et al. High capacity double-layer surface modified Li[Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂ cathode with improved rate capability. J Mater Chem, 2009, 19(28):4965
[34]	Lian F, Gao M, Ma L L, et al. The effect of surface modification on high capacity Li_1.375Ni_0.25Mn_0.75O_2+γ cathode material for lithium-ion batteries. J Alloys Compd, 2014, 608:158
[35]	Wu Y, Manthiram A. Effect of surface modifications on the layered solid solution cathodes (1-z) Li[Li_1/3Mn_2/3]O₂-zLi[Mn_0.5-yNi_0.5-yCo_2y]O₂. Solid State Ionics, 2009, 180(1):50
[36]	Jin Y C, Duh J G. Fluorination induced the surface segregation of high voltage spinel on lithium-rich layered cathodes for enhanced rate capability in lithium ion batteries. ACS Appl Mater Interfaces, 2016, 8(6):3883
[37]	Kobayashi G, Irii Y, Matsumoto F, et al. Improving cycling performance of Li-rich layered cathode materials through combination of Al₂O₃-based surface modification and stepwise precycling. J Power Sources, 2016, 303:250
[38]	Kim D H, Sandi G, Croy J R, et al. Composite ‘layered-layered-spinel’ cathode structures for lithium-ion batteries. J Electrochem Soc, 2013, 160(1):A31
[39]	Luo D, Li G S, Fu C C, et al. A new spinel-layered Li-rich microsphere as a high-rate cathode material for Li-ion batteries. Adv Energy Mater, 2014, 4(11):1400062
[40]	Bian X F, Fu Q, Qiu H L, et al. High-performance Li (Li_0.18Ni_0.15Co_0.15Mn_0.52) O₂@Li₄M₅O₁₂ heterostructured cathode material coated with a lithium borate oxide glass layer. Chem Mater, 2015, 27(16):5745
[41]	Zhao E Y, Liu X F, Hu Z B, et al. Facile synthesis and enhanced electrochemical performances of Li₂TiO₃-coated lithium-rich layered Li_1.13Ni_0.30Mn_0.57O₂ cathode materials for lithium-ion batteries. J Power Sources, 2015, 294:141
[42]	Jung Y S, Cavanagh A S, Yan Y F, et al. Effects of atomic layer deposition of Al₂O₃ on the Li[Li_0.20Mn_0.54Ni_0.13Co_0.13]O₂ cathode for lithium-ion batteries. J Electrochem Soc, 2011, 158(12):A1298
[43]	Liu H, Du C Y, Yin G P, et al. An Li-rich oxide cathode material with mosaic spinel grain and a surface coating for high performance Li-ion batteries. J Mater Chem A, 2014, 2(37):15640
[44]	Wu F, Li N, Su Y F, et al. Ultrathin spinel membrane-encapsulated layered lithium-rich cathode material for advanced Li-ion batteries. Nano Lett, 2014, 14(6):3550
[45]	Wu Y, Murugan A V, Manthiram A. Surface modification of high capacity layered Li[Li_0.2Mn _0.54Ni_0.13Co_0.13]O₂cathodes by AlPO₄. J Electrochem Soc, 2008, 155(9):A635