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Volume 12 Issue 2
Nov.  2021
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Article Contents
Zhang Puqiang, Wu Jixun, Zhang Wenqi, Lu Xinying. Pitting Mechanism of Passive 304 Stainless Steel in Weakly Basic Media Containing Chlorion[J]. Chinese Journal of Engineering, 1990, 12(2): 142-147. doi: 10.13374/j.issn1001-053x.1990.02.027
Citation: Zhang Puqiang, Wu Jixun, Zhang Wenqi, Lu Xinying. Pitting Mechanism of Passive 304 Stainless Steel in Weakly Basic Media Containing Chlorion[J]. Chinese Journal of Engineering, 1990, 12(2): 142-147. doi: 10.13374/j.issn1001-053x.1990.02.027

Pitting Mechanism of Passive 304 Stainless Steel in Weakly Basic Media Containing Chlorion

doi: 10.13374/j.issn1001-053x.1990.02.027
  • Received Date: 1989-04-12
    Available Online: 2021-11-15
  • Publish Date: 2021-11-15
  • The pitting behavior of passive 304 stainless steel in pH8.4, H3BO3 (0.2mol/l)-Na2B4O7 (0.05mol/l) and pH9.2, Na2B4O7 (0.05mol/l) solutions containing chlorion has been investigated using impedance technique. The possible reaction mechanism as well as the corresponding equivalent circuit model is presented. It is proposed that an intermediate complex (MOHCl) and its further adsorbed product (MOHCl-Cln-)ads will form during pit initiation and propagation stages.

     

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      沈陽化工大學材料科學與工程學院 沈陽 110142

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