熱噴涂制備非晶合金涂層性能的研究進展

辛蔚; 王玉江; 魏世丞; 王博; 梁義; 袁悅; 徐濱士

doi:10.13374/j.issn2095-9389.2020.11.20.001

熱噴涂制備非晶合金涂層性能的研究進展

doi: 10.13374/j.issn2095-9389.2020.11.20.001

陸軍裝甲兵學院再制造技術重點實驗室，北京 100072

基金項目: 國家重點研發計劃資助項目（2019YFC1908100）

詳細信息

通訊作者:
E-mail：yjwang201617@163.com

中圖分類號: TG131；TG174.442
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- 文章訪問數: 1350
- HTML全文瀏覽量: 861
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- 被引次數: 0
出版歷程
- 收稿日期: 2020-11-20
- 刊出日期: 2021-03-26

Research progress on the properties of amorphous alloy coatings prepared by thermal spraying

National Key Laboratory for Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China

More Information

Corresponding author: E-mail: yjwang201617@163.com

摘要

摘要: 首先介紹了非晶合金的理論基礎，然后從耐磨性和耐蝕性兩個方面入手，詳細地闡述了國內外對于熱噴涂非晶合金涂層性能研究進展情況，并系統地總結了非金合金涂層在耐磨性和耐蝕性上的本質聯系和根本矛盾，最后指出熱噴涂非晶合金涂層性能研究上的局限性，提出三點問題：對于非晶合金基礎理論的研究還處在起步階段、熱噴涂制備非晶合金涂層的合金體系種類少、制備非晶合金涂層的熱噴涂技術有待開發，并針對以上三點問題提出熱噴涂制備非晶合金涂層性能研究的未來發展方向。
- 非晶合金 /
- 熱噴涂 /
- 耐磨性 /
- 耐蝕性
Abstract: Amorphous alloys due to their unique microstructures exhibit high hardness, high strength, high wear resistance, high corrosion resistance, and a series of excellent properties, such as magnetic properties, hydrogen storage properties, and superconductivity. They have found application as a new generation of thermal spray materials, which are of interest in the engineering field. Since the 1980s, the preparation and application of bulk amorphous alloys have gradually become a research hotspot. However, preparing bulk amorphous alloys is seriously difficult and they have limited applications, hindering the replacement of conventional alloys and their wide use in various industries. As alternatives, amorphous alloy coatings have recently garnered research interest because of their similar properties to the bulk, lower cost, and wider applications. They are usually prepared by thermal spraying, which has great industrial applications. This article first introduced the theoretical framework of amorphous alloys and then the two aspects of wear resistance and corrosion resistance, expounded the research progress on the properties of thermally sprayed amorphous alloy coatings in detail, and systematically summarized the essential connection and fundamental contradiction of the wear resistance and corrosion resistance of amorphous alloy coatings. Finally, the limitations of thermal spraying for preparing amorphous alloy coatings were pointed out. Three problems are raised: (1) The basic theory of amorphous alloys is still in its infancy; (2) There are few types of alloy systems for preparing thermally sprayed amorphous alloy coatings; (3) The thermal spraying technology for preparing amorphous alloy coatings needs to be developed. Aiming at the above three problems, future research directions on the properties of thermally sprayed amorphous alloy coatings were proposed.
- amorphous alloy /
- thermal spraying /
- wear resistance /
- corrosion resistance

HTML全文

圖 1 非晶和晶體的形成過程^[27]

Figure 1. Diagram of the formation of amorphous and crystal materials^[27]

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圖 2 不同載荷下摩擦系數隨滑動時間的變化^[29]。（a）非晶合金涂層（ASC）；（b）不銹鋼涂層（SSC）

Figure 2. Variation of COFs with sliding time^[29]: (a) amorphous steel coating; (b) stainless steel coating

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圖 3 不同送粉率下涂層的X射線衍射圖譜^[30]

Figure 3. XRD patterns of the various high-velocity oxygen-fuel sprayed coatings prepared with different powder feed rates^[30]

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圖 4 不同條件下實驗樣品的磨損率和摩擦系數^[31]

Figure 4. Wear rates and friction coefficients of the tested samples^[31]

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圖 5 不同熱處理溫度下涂層磨損量與H/E_r的關系^[32]

Figure 5. Relationship between the wear loss and the H/E_r ratio for the coating^[32]

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圖 6 不同摩擦學條件下鐵基非晶合金涂層和基體的磨損率^[33]

Figure 6. Wear rates of Fe-based amorphous coatings and the reference 316L crystalline steels under various sliding conditions^[33]

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圖 7 鐵基非晶合金涂層在不同條件下的高溫摩擦學模擬圖^[33]。（a）真空；（b）大氣

Figure 7. Modeling illustrations of the elevated-temperature tribology process for the Fe-based ACs^[33]: (a) vacuum; (b) air

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圖 8 鐵基非晶合金涂層磨損機理圖^[34]

Figure 8. Schematic diagram showing the wear mechanisms in the Fe-based amorphous coating^[34]

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圖 9 涂層、316L鋼和1045鋼在質量分數3.5% NaCl溶液中的動電位極化曲線^[35]

Figure 9. Potentiodynamic polarization curves of the high-velocity air-fuel coating, 316L steel, and 1045 steel in mass fraction of 3.5% NaCl solution^[35]

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圖 10 電化學試驗后的表面形貌圖^[36]. 2 mol·L^?1 NaOH溶液中的涂層（a）和不銹鋼（b）；3.5% NaCl溶液中的涂層（c）和不銹鋼（d）

Figure 10. SEM images of surfaces after the electrochemical test^[36]: coating (a) and stainless steel (b) in 2 mol·L^?1 NaOH solution; coating (c) and stainless steel (d) in 3.5% NaCl solution

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圖 11 不同噴涂功率下的非晶合金涂層、基體和鍍鋅鋼的動電位極化曲線^[37]

Figure 11. Potentiodynamic polarization curves of the Fe-based composite coatings, deposited with various plasma powers, in comparison with galvanized steel and mild steel substrate^[37]

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圖 12 腐蝕條件下退火溫度對質量損失的影響^[39]

Figure 12. Effect of annealing temperature on the mass loss^[39]

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圖 13 涂層性能表征。（a）質量隨浸泡時間的變化；（b）涂層的差示掃描量熱分析曲線^[41]

Figure 13. Performance characterization of coating: (a) mass as a function of immersion time; (b) DSC curve of the outer Fe-based amorphous coating^[41]

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