鈦/鋼復合板及其制備應用研究現狀與發展趨勢

白于良; 劉雪峰; 王文靜; 楊耀華

doi:10.13374/j.issn2095-9389.2020.08.31.007

鈦/鋼復合板及其制備應用研究現狀與發展趨勢

doi: 10.13374/j.issn2095-9389.2020.08.31.007

白于良¹,
劉雪峰^{1, 2, 3, ,},
王文靜^{1, 3},
楊耀華¹

1.
北京科技大學材料科學與工程學院，北京 100083
2.
北京科技大學現代交通金屬材料與加工技術北京實驗室，北京 100083
3.
北京科技大學材料先進制備技術教育部重點實驗室，北京 100083

基金項目: 國家重點研發計劃資助項目（2018YFA0707300）

詳細信息

通訊作者:
E-mail：liuxuefengbj@163.com

中圖分類號: TG335.81
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- 被引次數: 0
出版歷程
- 收稿日期: 2020-08-31
- 刊出日期: 2021-01-25

Current status and research trends in processing and application of titanium/steel composite plate

BAI Yu-liang¹,
LIU Xue-feng^{1, 2, 3
, ,},
WANG Wen-jing^{1, 3},
YANG Yao-hua¹

1.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
2.
Beijing Laboratory of Metallic Materials and Processing for Modern Transportation, University of Science and Technology Beijing, Beijing 100083, China
3.
Key Laboratory for Advanced Materials Processing of Ministry of Education, University of Science and Technology Beijing, Beijing 100083, China

More Information

Corresponding author: E-mail: liuxuefengbj@163.com

摘要

摘要: 隨著鈦/鋼復合板的應用領域不斷拓展，市場對鈦/鋼復合板的尺寸和性能都提出了新的要求，現有的制備方法和工藝也面臨著巨大挑戰。本文從原材料情況、復合板尺寸、界面特征和力學性能等方面概述了鈦/鋼復合板研究現狀，評述了鈦/鋼復合板目前的主要制備方法及其優缺點，綜述了表面處理方法、熱軋溫度、過渡層金屬和熱處理工藝對鈦/鋼復合板界面結合質量的影響，闡述了鈦/鋼復合板的應用現狀，指出了鈦/鋼復合板面臨的主要問題及未來的重點研究方向。
- 鈦/鋼復合板 /
- 制備方法 /
- 應用領域 /
- 過渡層 /
- 界面結合質量
Abstract: Titanium/steel composite plate is an advanced metal-layered composite material, which is composed of titanium or titanium alloy as the cladding material and carbon steel or stainless steel as the base material. Titanium/steel composite plate is widely used in petrochemical, electric power, salt chemical, seawater desalination, and ocean engineering since it has excellent corrosion resistance of the cladding material and the characteristics of high strength and low cost of the base material. Various methods have been adopted for manufacturing titanium/steel composite plates, including explosive bonding, explosive-rolling bonding, diffusion bonding, and hot rolling bonding. However, with the continuous expansion of the application field of titanium/steel composite plate, demands on new requirements on the material’s size, interface bonding quality, and mechanical properties are difficult to meet with the existing preparation methods and processes of titanium/steel composite plate. Thus, it is necessary to study the interface recombination mechanism and interface precipitation behavior, improve the interface bonding quality, and develop novel preparation methods. In response, this paper summarized the research and development status of titanium/steel composite plates based on different aspects such as raw materials, composite plate size, interface characteristics, and mechanical properties. The main processing methods of titanium/steel composite plate were also reviewed. The influence of surface treatment method, hot rolling temperature, transition layer metal, and heat treatment process on the interface of titanium/steel composite plate was summarized, and the application status and development trend of titanium/steel composite plate were described. Finally, the main problems and future research direction of titanium/steel composite plate were pointed out. This study aims to provide a reference for in-depth theoretical research of titanium/steel composite plate, promote its progress preparation technology, and broaden its application field.
- titanium/steel composite plate /
- processing method /
- application field /
- transition layer /
- interfacial bonding strength

HTML全文

圖 1 爆炸復合法裝配示意圖^[40]

Figure 1. Assembly diagram of explosive composite method^[40]

下載: 全尺寸圖片幻燈片

圖 2 小孔抽真空組坯示意圖^[59]

Figure 2. Schematic of small hole vacuum assembling^[59]

下載: 全尺寸圖片幻燈片

圖 3 真空電子束焊接組坯熱軋復合過程示意圖^[21]

Figure 3. Schematic of vacuum electron beam welding and hot rolling bonding process^[21]

下載: 全尺寸圖片幻燈片

圖 4 不同熱軋復合制備的鈦/鋼復合板的界面形貌及高倍形貌^[25]。（a,e）850 ℃；（b,f）900 ℃；（c,g）950 ℃；（d,h）1000 ℃

Figure 4. Interface morphology of titanium/steel composite plate prepared at different hot rolling temperatures^[25]: (a,e) 850 ℃; (b,f) 900 ℃; (c,g) 950 ℃; (d,h) 1000 ℃

下載: 全尺寸圖片幻燈片

表 1 鈦和鋼的物理性能^[2]

Table 1. Physical properties of titanium and steel^[2]

Material	Density/ (g·cm^?3)	Melting point/℃	Thermal conductivity/ (W·m^?1·K^?1)	Thermal expansion coefficient/ (10^?6·K^?1)	Specific heat/ (J·kg^?1·K^?1)
Ti	4.5	1677	13.8	8.2	539
Fe	7.8	1537	66.7	11.8	482

下載: 導出CSV

表 2 鈦/鋼界面各相的晶體學信息

Table 2. Crystallographic information of phases in titanium/steel interface

Phase	Crystal system	Space group	lattice constant
α-Fe	BCC	Im-3m	a = 0.2866 nm
α-Ti	HCP	P63/mmc	a = b = 0.2951 nm， c = 0.4683 nm
β-Ti	BCC	Im-3m	a = 0.3306 nm
TiC	FCC	Fm-3m	a = 0.4327 nm
Fe₂Ti	HCP	P63/mmc	a = b = 0.4785 nm， c = 0.7799 nm
FeTi	BCC	Pm-3m	a = 0.2976 nm

下載: 導出CSV

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