核殼結構復合吸波材料研究進展

黃威; 魏世丞; 梁義; 王博; 黃玉煒; 王玉江; 徐濱士

doi:10.13374/j.issn2095-9389.2019.05.001

核殼結構復合吸波材料研究進展

doi: 10.13374/j.issn2095-9389.2019.05.001

陸軍裝甲兵學院裝備再制造技術國防科技重點實驗室, 北京 100072

詳細信息

通訊作者:
王玉江, E-mail: hitwyj@126.com

中圖分類號: TB34
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出版歷程
- 收稿日期: 2018-11-21
- 刊出日期: 2019-05-01

Research progress of core-shell composite absorbing materials

National Key Laboratory for Remanufacturing, Academy of Army Armored Forces, Beijing 100072, China

More Information

Corresponding author: WANG Yu-jiang, E-mail: hitwyj@126.com

摘要

摘要: 在綜述電磁波材料吸波工作原理的基礎上, 討論了核殼結構材料在吸波領域的優勢.重點介紹了近年來不同類型核殼結構復合吸波材料的研究進展, 主要包括鐵氧體型、磁性金屬微粉及其氧化物型、陶瓷型、導電聚合物型、碳系材料型等核殼結構復合吸波材料.同時對不同類型的核殼結構吸波材料的制備方法、組織結構和微波吸收性能進行了詳細的歸納評述.最后對核殼結構復合吸波材料的發展趨勢進行了展望, 主要包括多層核殼結構, yolk-shell結構以及與其他材料結構相復合的特殊結構, 為進一步研究核殼結構復合吸波材料提供參考.
- 核殼 /
- 吸波 /
- 結構 /
- 復合 /
- 性能
Abstract: With the rapid development of anti-stealth technology and the iterative renewal of firepower destruction weapons, the battlefield survivability of modern weapons and equipment has been severely tested. In the modern warfare of over-the-horizon, radar detection technology is currently the most widely used method; therefore, reducing the radar echo signal is the most important factor to improve the stealth ability of weapon equipment. Generally, stealth technology is divided into structural stealth and material stealth. Reasonable shape structure design can reduce the radar cross section (RCS) value of a weapon equipment. However, due to the high cost of shape structure and the easy reduction of the comprehensive performance of equipment, there are many limitations in application. Because the stealth technology of materials is relatively simple and the design difficulty is relatively low, the research and application of stealth materials are popular and have been well explored. Although the traditional absorbing materials have the advantages of low cost, good flexibility, and easy processing, they also have the defects of high density, narrow working frequency band, and limited strength. Core-shell microwave absorber is a composite multiphase structure with a spherical particle as the core and one or more layers of heterogeneous materials coated on the outer surface. Because of its unique structure and excellent performance, it is a promising material to solve the existing problems. On the basis of reviewing the working principle of microwave absorbing materials, the advantages of core-shell structure materials in the field of microwave absorbing were discussed. This paper mainly introduced the research progress of different types of core-shell structure microwave absorbing materials explored in recent years as well as summarized and commented on their preparation methods, structure, and microwave absorbing properties; these materials are mainly based on ferrite, magnetic metal powder and its oxide, ceramic, conductive polymer, and carbon series materials. Finally, the development trend of core-shell structure mircrowave absorbing materials was predicted, including multi-layer core-shell structure, yolk-shell stucture and special structure combined with other structures, whisch can provide reference for futher study of core-shell shtucture composite absorbing materials.
- core-shell /
- microwave absorption /
- structure /
- composite /
- property

HTML全文

圖 1 C@MnO₂電子顯微全息分析圖. (a) 原始透射電鏡圖; (b) 電子全息重構的電荷分布圖; (c) 全息圖框中區域放大圖^[25]

Figure 1. Electron microscopic hologram of C@MnO₂: (a) original TEM image; (b) charge distribution map reconstructed by electron holography; (c) enlarged view of the boxed region of the hologram^[25]

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圖 2 Co@CoO復合材料反射曲線圖. (a) 無孔; (b) 有孔^[37]

Figure 2. Reflection curves of Co@CoO composite: (a) nonporous; (b) porous^[37]

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圖 3 Fe₃O₄@MnO₂微觀形貌圖. (a) 蘑菇狀; (b) 蜂窩狀; (c) 花冠狀^[39]

Figure 3. Morphology of Fe₃O₄@MnO₂: (a) mushroom-like; (b) honeycomb-like; (c) corolla-like^[39]

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圖 4 透射電鏡形貌. (a) CoFe₂O₄空心球; (b) CoFe₂O₄@CNTs ^[50]

Figure 4. TEM images: (a) CoFe₂O₄ hollow sphere; (b) CoFe₂O₄@CNTs ^[50]

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圖 5 Ni@SnO₂@PPy合成示意圖^[51]

Figure 5. Schematic illustration of formation process of Ni@SnO₂@PPy composite^[51]

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圖 6 Ni@Void@SnO₂(Ni₃Sn₂)不同時間下的微觀形貌及形成過程. (a) 3 h; (b) 6 h; (c) 10 h; (d) 15 h; (e) Ni@Void@SnO₂(Ni₃Sn₂)形成過程示意圖^[54]

Figure 6. TEM images of Ni@Void@SnO₂(Ni₃Sn₂) at different hydrothermal time and the formation process: (a) 3 h; (b) 6 h; (c) 10 h; (d) 15 h; (e) schematic diagram of the formation process of Ni@Void@SnO₂(Ni₃Sn₂) ^[54]

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圖 7 Fe₃O₄@BaTiO₃/RGO合成路線^[56]

Figure 7. Schematic illustration of the synthesis process of Fe₃O₄@BaTiO₃/RGO nanocomposites^[56]

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