Thermal equilibrium analysis and experiment of molten slag modification by use of its sensible heat
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摘要: 采用熱態改質方法可直接將冶金熔渣制備成高附加值材料,從而實現熔渣的"熱""渣"雙利用,因此這一方法在熔渣資源化利用領域中已成為研究熱點.本文選取熔融鋼渣和河沙分別為典型熔渣和改質劑,模擬計算分析在1600℃熔渣內摻入改質劑的過程中改質劑摻量對改質熔渣顯熱的影響,并對研究結果進行工業試驗驗證.研究表明:隨著改質劑摻入,改質熔渣顯熱呈現先增加后減小的趨勢;隨改質劑摻量由5%增加到11%時改質熔渣顯熱反而增加,當改質劑摻量為11%時改質熔渣顯熱達到最大.從熔渣顯熱利用和改質效果綜合考慮,改質劑摻量的理論最佳區間為11%~19%.現場試驗表明,摻入12%左右的河沙后,改質熔渣流動性好,冷卻渣安定性等性能改善顯著.Abstract: Preparing high added-value materials from molten slag directly by modifying molten slag has drawn a great interest in the utilization of molten slag because of its high efficiency during the integrated utilization of the heat and slag. In this paper,molten steel slag and sands were selected as typical molten slag and modifiers,respectively. The effects of the amount of added modifiers on the waste liquid sensible heat of modified molten slag were studied during the modification process,which was subsequently confirmed by industrial test. It is indicated that the sensible heat of modified molten slag increases at first and then decreases with the addition of modifiers. The sensible heat improves with the increase in mass fraction of modifiers from 5% to 11% and reaches the maximum at the mass fraction of 11%. The optimal amount of modifiers ranges from 11% to 19% in consideration of both the utilization of sensible heat and the performance of modified molten slag. Furthermore,the industrial test verifies that both the fluidity of modified molten slag and the stability of cooled modified slag are significantly improved at the addition of about 12% modifiers.
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Key words:
- molten slag /
- sensible heat /
- modification /
- thermal equilibria /
- industrial test
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