Safety evaluation of pipeline steels under SNG containing H2
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摘要: 煤制天然氣是我國煤炭清潔利用的重要發展方向.現有管道用于輸送煤制天然氣(最高氫分壓為0.72 MPa)時需要考慮其中低壓氫氣的影響,因而需先進行氫致開裂安全性評估.本文利用高壓釜環境下恒載荷實驗和電化學充氫,模擬研究X-70管線鋼和20#鋼在不同氫含量下的氫損傷和氫致延遲開裂,并對其在煤制天然氣中服役安全性進行評估.在總壓12MPa(10 MPa N2+2 MPa H2)的高壓釜中放置一個月,兩種鋼的金相試樣均不出現氫損傷,U彎試樣不開裂,加屈服強度σs的恒載荷試樣不發生斷裂.在含0.72 MPa的煤制天然氣中長期服役時,進入兩種鋼的氫含量均遠低于σs下發生氫致延遲開裂的門檻氫含量和出現氫損傷的門檻氫含量,因而X-70鋼和20#鋼在煤制天然氣中長期服役均具有高的氫損傷和氫致開裂安全系數.Abstract: Synthetic natural gas(SNG) is an important developing direction of the clean utilization of coal. The present pipeline steel may cause hydrogen-induced delayed cracking when used to transit SNG due to the hydrogen partial pressure in SNG perhaps up to 0.72 MPa. Therefore,the safety assessment of pipeline steel for long-term service is very important and necessary. In this work,hydrogen damage and hydrogen-induced delayed cracking in X-70 pipeline steel and 20#steel at different hydrogen contents were studied by using autoclave constant load test and electrochemical hydrogen charging methods. The service safety of the steels in SNG was evaluated. There is no hydrogen damage in the two kinds of steel after being placed in the autoclave in which the total pressure 12 MPa(10 MPa N2+ 2 MPa H2) is kept for one month. Hydrogen-induced delayed cracking does not occur in the U-bending specimen. And the constant load samples do not fail after they are kept at the yield stress for one month. The hydrogen content entering into X-70 and 20# samples is much lower than the threshold hydrogen content for hydrogen-induced delayed cracking and that for hydrogen damage.Therefore,both X-70 steel and 20# steel have high safety factors during the long-term service of transiting SNG.
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