鋅鋁池中Si含量對渣相形成的影響

涂浩; 潘修河; 吳長軍; 蘇旭平; 劉亞; 王建華

doi:10.13374/j.issn2095-9389.2016.07.008

鋅鋁池中Si含量對渣相形成的影響

doi: 10.13374/j.issn2095-9389.2016.07.008

涂浩^1,2,
潘修河^1,2,
吳長軍^1,2,
蘇旭平^1,2,
劉亞^1,2,
王建華^1,2, ,

1. 常州大學材料表面科學與技術重點實驗室, 常州 213164;
2. 常州大學光伏科學與工程協同創新中心, 常州 213164

基金項目:

國家自然科學基金資助項目(51271041

江蘇高校優勢學科建設工程資助項目

51271040)

詳細信息

通訊作者:
王建華,E-mail:wangjh@cczu.edu.cn

中圖分類號: TG174.4
計量
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- 被引次數: 0
出版歷程
- 收稿日期: 2015-07-23
- 網絡出版日期: 2021-07-22

Effect of Si content in the zinc-aluminium bath on the formation of slag phase

TU Hao^1,2,
PAN Xiu-he^1,2,
WU Zhang-jun^1,2,
SU Xu-ping^1,2,
LIU Ya^1,2,
WANG Jian-hua^{1,2
, ,}

1. Key Laboratory of Material Surface Science and technology, Changzhou University, Changzhou 213164, China;
2. Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou 213164, China

摘要

摘要: 采用Thermo-Calc軟件分別計算硅在不同溫度Zn-50%Al-xFe-ySi(原子數分數)熔池液相中的溶解度及不同溫度Zn-30%Al-2%Fe-xSi(質量分數)熔池中開始形成τ₅渣相和FeAl₃渣相消失時該熔池中硅含量,采用平衡合金法測定Zn-50%Al-xFe-ySi合金液相中硅的溶解度和不同硅含量的Zn-30%Al-2%Fe-xSi合金的相平衡關系.當溫度分別為540、560、580、600和620℃時,硅在Zn-50%Al-xFe-ySi體系液相中的溶解度(原子數分數)計算值分別為0.82%、0.95%、1.11%、1.28%和1.47%,實驗結果與計算結果吻合很好.當熔池溫度分別為580、600和620℃時,在Zn-30%Al-2%Fe-xSi合金中剛開始出現τ₅相時所對應硅質量分數的計算值分別為0.6%、0.72%和0.84%,發生FeAl₃相消失對應的鋅池中硅質量分數的計算值分別為1.12%、1.22%和1.34%,實驗結果與計算預測結果基本一致.
- 熱浸鍍鋅 /
- 硅含量 /
- 熱力學計算 /
- 渣
Abstract: The solubility of silicon in a Zn-50%Al-xFe-ySi(in atomic fraction) molten bath and the content of silicon in a Zn-30%Al-2%Fe-xSi(in mass fraction) molten bath corresponding to the appearing of τ₅ slag phase and the disappearing of FeAl₃ phase were calculated at different temperatures using the Thermo-Calc software. At the same time,the solubility of silicon in liquid phase in the Zn-50%Al-xFe-ySi alloy and the phase equilibrium relationship of the Zn-30%Al-2%Fe-xSi alloy were experimentally determined by using the equilibrium alloy method. The results show that the calculated solubility of silicon in liquid phase in the Zn-50%Al-xFe-ySi system at 540,560,580,600 and 620℃ are 0.82%,0.95%,1.11%,1.28% and 1.47%,respectively,which agree well with the experimental data. When the temperature of the molten bath is 580,600,and 620℃,the calculated content of silicon in the Zn-30%Al-2%Fe-xSi alloy corresponding to the appearing of τ₅ phase in the molten bath is 0.6%,0.72% and 0.84%,and the values corresponding to the disappearing of FeAl₃ phase are 1.12%,1.22% and 1.34%,respectively,which agree basically with the experimental results.
- hot dip galvanizing /
- silicon content /
- thermodynamic calculations /
- slag