Evolution of γ' precipitates in GH720Li alloy during long-term aging
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摘要: 研究GH720Li合金經標準熱處理(1105℃,4 h→油冷+650℃,24 h→空冷+760℃,16 h→空冷)后分別在720℃時效0~5000 h和800℃時效0~1000 h后γ!強化相的演變規律.合金在720℃,5000 h時效后一次γ'相的尺寸、形態以及數量基本不發生變化;在720℃,200 h時效后,二次γ'相發生明顯粗化;500 h后出現不均勻長大.相應地,500 h前硬度下降速率大,500 h后趨于平穩.在800℃,500 h時效后,一次γ'相發生粗化;800℃,100 h時效后,二次γ'相發生明顯粗化且不均勻長大.500 h前硬度下降斜率很大,500 h后硬度仍有明顯下降趨勢.720℃及800℃時二次γ'相粗化行為是以擴散控制的粗化機制為主導.γ'相平均半徑與時效時間滿足立方根關系,符合L-S-W(Lifshiz-Slyozov-Wanger)理論.Abstract: A standard heat treatment(1105℃/4 h/(oil cooling) + 650℃/24 h/(air cooling) + 760℃/16 h/(air cooling)) and a subsequent long term exposure at temperatures of 720℃ for 0-5000 h and 800℃ for 0-1000 h were proposed to investigate the microstructural evolution of γ' precipitates in GH720 Li alloy. The size,morphology and quantity of the primary γ' phase have no significant variation at 720℃. However,at the same temperature,obvious grain coarsening and the grain size inhomogeneity of secondary γ'particles appear with the aging time up to 200 h and 500 h,respectively. The descending slope of hardness decreases first and when the aging time exceeds 500 h it flattens. At 800℃,the primary γ' phase coarsens after 500 h of aging,while both obvious grain coarsening and the grain size inhomogeneity of secondary γ' particles happen after 100 h of long term exposure. The descending slope of hardness decreases first,and unlike the results at 720℃,it is still downward when the aging time exceeds 500 h. The coarsening behavior is controlled by lattice diffusion. There shows a linear relationship between the average radius of the γ' phase and the cube root of aging time,which accords with the L-S-W(Lifshiz-Slyozov-Wanger) theory.
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Key words:
- nickel base superalloys /
- aging /
- precipitates /
- coarsening
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