Effect of BOF slag composition on the end-point[C]content of ultra-low carbon steel
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摘要: 采用共存理論、動力學分析和實驗驗證的方法,研究轉爐冶煉超低碳鋼吹煉末期爐渣成分對終點[C]含量的影響規律,建立1853-1973 K時終點[C]與爐渣成分和溫度的回歸模型.結果表明:FeO活度受溫度影響較小,主要受爐渣成分的影響;脫碳動力學條件主要受爐渣成分和溫度的影響.爐渣堿度增加,終點[C]含量升高;渣中FeO含量增加,終點[C]含量迅速降低,渣中FeO質量分數應控制在12.0%-18.0%之間;渣中MgO質量分數在7.0%-13.0%范圍內逐漸增加,鋼液中[C]質量分數增加值不足0.01%;隨著溫度的增加,鋼液中[C]含量降低.回歸模型對冶煉超低碳鋼的轉爐終點[C]含量的預判平均誤差率為±15.25%,[C]含量誤差在±0.01%以內的爐次占69.19%.Abstract: The effect of slag composition on the[C] content of ultra-low carbon steel at the end of smelting was investigated by the coexistence theory,dynamics analysis and experimental verification. A regression model of end-point[C] content was established with temperature and slag composition in a temperature range from 1853 K to 1973 K. The results show that the Fe O activity is little affected by temperature,while it is mainly affected by slag composition. However,the decarburization kinetics is mainly affected by slag composition and temperature. The end-point[C] content increases with increasing slag basicity,but it quickly decreases with increasing Fe O content in slag,so the end-point Fe O mass fraction in slag should be controlled in 12%-18%. In addition,the increment value of[C] is less than 0. 01% with the Mg O mass fraction in slag from 7% to 13%. The results also show that the end-point[C]mass fraction decreases with increasing temperature. Compared with industrial results,the average error rate of the regression model for the end-point[C] content in the ultra-low carbon steel is ±15. 25%,and the hit rate to[C] content predicted by the regression model reaches 69. 19% with a control precision of ±0. 01% for heats of the experiment.
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Key words:
- steelmaking /
- low carbon steel /
- slag composition /
- carbon content /
- regression models
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