Fretting corrosion characteristics of NC30Fe alloy in a sodium chloride solution
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摘要: 在PLINT微動磨損試驗機上附加電化學測試系統,采用十字交叉接觸方式,位移幅值為100μm,法向載荷20、50和80 N條件下,研究NC30Fe合金傳熱管在氯化鈉溶液中的微動腐蝕行為.使用電化學工作站記錄微動腐蝕過程中開路電位變化,運用電位掃描法測量微動過程的極化曲線;采用掃描電子顯微鏡觀察磨痕的表面形貌,光學輪廓儀測定磨痕的三維形貌及磨損量.微動磨損使損傷區域金屬原子活性增大,腐蝕傾向增大,加速了NC30Fe合金的腐蝕.在氯化鈉溶液中,NC30Fe合金由于微動磨損過程產生腐蝕產物膜起到潤滑減摩作用,摩擦系數較純水中降低;但因腐蝕與磨損的交互作用,在氯化鈉溶液中的磨損量比純水中高.氯化鈉溶液中的磨損機制主要表現為磨粒磨損和剝層的共同作用.Abstract: By adding an electrochemical test system on a PLINT fretting wear test machine,the fretting corrosion behavior of an NC30 Fe heat transfer tube in a sodium chloride solution was investigated using cross-contacting configuration under different loading conditions,i. e.,three different normal loads of 20,50 and 80 N with a 100 μm reciprocating amplitude. An electrochemical workstation was used to record the open circuit potential during the fretting corrosion process,and the polarization curves were measured by the potential scanning method. The morphology of wear scars was observed by scanning electron microscopy. The 3D morphology and wear volume loss were determined by optical profilometry. It is found that metal atoms in the worn area are more active and more prone to corrosion because of fretting motion,leading to accelerated corrosion of NC30 Fe alloy. As a result of lubrication action by the corrosion product film,the friction coefficient in the sodium chloride solution is smaller than that in pure water. However,the wear volume loss in the sodium chloride solution is greater than that in pure water due to the interaction of corrosion and wear. Abrasive wear and delamination are considered to be the main wear mechanism in the sodium chloride solution.
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