Effect of aging approaches on the aging behavior of polyurethane coated steels
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摘要: 運用四種加速方法對聚氨酯有機涂層鋼板進行老化,并通過涂層的表觀性能和電化學特征對比研究了老化方式對涂層失效的影響.紫外老化對涂層光澤的影響最大,老化32 d失光度達85.7%.鹽霧實驗前期線性極化阻力Rp迅速下降,后期由于鹽膜的生成使得Rp保持穩定;氙燈和鹽霧混合老化的光澤度和Rp的變化規律都表現為實驗前期與光老化相似,后期則與鹽霧實驗相類似.此外,擬合不同老化方式的電化學交流阻抗譜發現:混合老化前期主要受氙燈影響,與單一氙燈老化的等效電路一致,表現為兩個時間常數;后期產生鹽膜,出現三個時間常數.Abstract: Four accelerated weathering tests were carried out on polyurethane coated steels. The apparent properties and electro-chemical characteristics of the coatings were studied to compare the effects of different accelerated weathering tests on the coating fail-ure behavior. It is found that UV exerts the greatest influence on the glossiness of the coatings and the gloss loss reaches up to 85.7% after 32 d aging. The linear polarization resistance decreases rapidly in the early period of the salt spray test and stabilizes in the later period due to the formation of a salt film. In the mixed aging (xenon light aging+salt spray) test, the variation tendency of both gloss loss and linear polarization resistance are similar to those presented in the early period of xenon light aging and similar to those presen-ted in the later period of salt spray test. Moreover, the equivalent circuit of the mixed aging test shows two time constants in the early period, which is consistent with the single xenon light aging test. In the later period, the failure process of the coatings can be mani-fested with three time constants, in which the formation of a salt film is the typical feature.
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Key words:
- steel corrosion /
- polyurethane /
- coatings /
- accelerated aging /
- aging behavior
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