Preparation of glass-ceramics from molten blast furnace slag
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摘要: 采用熔融法,由熔融高爐渣制備性能穩定的基礎玻璃.通過對基礎玻璃的差熱分析確定微晶玻璃的熱處理工藝制度.結合X射線衍射分析、掃描式電子顯微鏡觀察等現代研究方法,確定了微晶玻璃熱處理制度的最佳工藝參數,并研究了微晶玻璃的晶體生長方式.微晶玻璃的熱處理最佳工藝參數為:核化溫度850℃,保溫1.5 h;晶化溫度935℃,保溫1 h.玻璃首先從表面開始析晶,然后逐步向內部生長.實驗所得微晶玻璃的力學性能,如抗折強度、耐酸堿性和硬度,均優于天然大理石.Abstract: Basic glass with stable properties was prepared from molten blast furnace slag by using the melting method. The heat treatment regime of glass-ceramics was determined by differential thermal analysis of the basic glass. Optimum heat treatment parameters were selected and the crystal growth pattern of glass-ceramics was analyzed by X-ray diffraction and scanning electron microscopy.The results show that the optimum heat treatment parameters of glass-ceramics are the nucleation temperature of 850℃ for 1.5 h and the crystallization temperature of 935℃ for 1 h. The crystallization grows from the surface to interior gradually. The mechanical properties of the prepared glass-ceramics,such as bending strength,acid and alkali resistance,and hardness,are better than those of ordinary marble.
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Key words:
- blast furnace slag /
- glass-ceramics /
- heat treatment /
- crystal growth /
- mechanical properties /
- waste utilization
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