Corrosion behavior of carbon steel pipelines under different deposits in oil and gas transportation
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摘要: 利用失重法、電化學測試、絲束電極和微觀分析手段研究了在CO2飽和地層水中X65碳鋼覆蓋不同沉積物的腐蝕行為.結果顯示,覆蓋沙粒、黏土和碳酸亞鐵可減輕X65鋼的腐蝕,而覆蓋硫化亞鐵、元素硫和混合物則明顯加速鋼的腐蝕.尤其是覆蓋元素硫,試樣的腐蝕速率急劇增大.覆蓋混合物試樣的腐蝕速率也有顯著的增大,混合物中元素硫起主導作用.試樣表面沉積的元素硫可自催化陰極反應而大大加速鋼的腐蝕.絲束電極的電位和電流分布顯示,覆蓋混合沉積物的電極,其電極電位比無沉積物覆蓋電極的電極電位正.隨著腐蝕進行,沉積物覆蓋下電極發生嚴重的局部腐蝕.絲束電極的電位和電流分布圖能夠有效反映沉積物下局部環境變化而導致的局部腐蝕行為差異.Abstract: The corrosion behavior of X65 carbon steel under different deposits in CO2 saturated formation water was studied by weight loss measurements, electrochemical measurements, wire beam electrode and microscopic analysis. The results show that the corrosion rate of the steel slightly decreases by being covered with sand, clay or ferrous carbonate. However, covered with ferrous sulfide, elemental sulfur or mixture, the corrosion rate obviously accelerates, especially in the specimen covered with elemental sulfur. The corrosion rate of the specimen covered with mixture deposits also significantly increases, in which elemental sulfur plays a dominant role. The significant increase in corrosion rate of the specimen covered with elemental sulfur is attributed to the self-catalytic action of elemental sulfur on the cathodic reaction of steel corrosion. The current and potential distributions of wire beam electrodes indicate that the potentials of the electrodes covered with mixture deposits are more positive than those without deposits. During the corrosion, severe localized corrosion occurs on the electrodes under mixture deposits. The current and potential maps of wire beam electrodes can effectively reflect the localized corrosion behavior of the steel under deposits due to the change of local environment.
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Key words:
- petroleum pipelines /
- steel corrosion /
- deposits /
- microscopic analysis /
- localized corrosion
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