Effect of prestrain on the degradation behaviour of aviation organic coatings
-
摘要:
借助有機涂層預應變施加方法,跟蹤觀察戶內加速試驗過程中受到外加應變的航空有機涂層表面形貌變化,利用環境掃描電子顯微鏡進行顯微組織表征,利用電化學阻抗譜進行特定頻率的阻抗模值分析,進而綜合研究航空有機涂層在外加應變和熱帶海洋大氣環境耦合作用下的損傷規律和失效模型.研究發現,外加拉應變導致有機涂層的防護性能下降,外加拉應變水平越高,有機涂層損傷越嚴重,防護性能下降越多.進行戶內加速試驗過程中,受到外加拉應變的涂層防護性能進一步下降,外加拉應變越大,下降越快.受外加拉應變的涂層防護性能下降的原因是相應的應力水平超過有機涂層材料的斷裂強度,從而在涂層內部形成微裂紋,構成外界溶液到達有機涂層/合金界面的通道.受到外加壓應變后,有機涂層的防護性能不發生明顯變化.進行戶內加速試驗過程中,受到外加壓應變的涂層防護性能緩慢喪失,受到外加壓應變水平越高,涂層防護性能下降越緩慢.
Abstract:The surface morphology of an aviation organic coating during indoor accelerated testing was continually observed by a prestrain method. Environmental scanning electron microscopy and electrochemical impedance spectroscopy were employed for micro-structural characterization and characteristic impedance modulus analysis to systematically study the degradation behavior and failure model of the organic coating under the co-effect of prestrain and tropical marine atmosphere. It is found that the protective properties of the organic coating show a dramatic decrease after tensile prestrain application and go further down during indoor accelerated testing;the degradation of the organic coating is positively correlated with the tensile prestrain level. It is thought that the loss of the protective properties is due to the relatively high stress level which exceeds the breaking strength of the organic coating materials, leading to the formation of microcracks, which serve as routes to the organic coating/alloy interface for solution. But the protective properties of the organic coating exhibit no change after compressive prestrain application and decrease slowly during indoor accelerated testing;the degradation of the organic coating is negatively correlated with the compressive prestrain level.
-
Key words:
- organic coatings /
- prestrain /
- degradation /
- protection /
- electrochemical impedance spectroscopy /
- microcracks
-

計量
- 文章訪問數: 191
- HTML全文瀏覽量: 36
- PDF下載量: 8
- 被引次數: 0