Ironmaking by direct reduction of iron ore-biomass composite pellets using biomass syngas
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摘要: 為了使煉鐵工業擺脫對化石能源的依賴及滿足越來越嚴格的環境要求,將生物質能的開發利用與直接還原技術進行集成提出一種新型的綠色煉鐵方法.把生物質、鐵礦石粉與添加劑混合制取生球團,利用生物質催化氣化制備的富氫合成氣作為還原劑,生物質的高溫燃燒為生球團的預熱和預熱球團的直接還原提供外加熱源.對影響生物質直接還原煉鐵的因素,如預熱、還原溫度及球團粒徑進行了研究,發現減小球團粒徑、增加預熱和還原溫度能夠提高直接還原鐵產品的全鐵質量分數及金屬化率.當采用品位65.21%的鐵精礦為原料,在最優操作條件下(生球團粒徑介于8~10 mm之間,900℃預熱30 min,1000℃下還原60 min)可制得全鐵TFe質量分數為86.1%,金屬化率為94.9%的高質量直接還原鐵產品.Abstract: In order to ease the shortage of fossil energy and to come up to the stricter effluent standard, this article introduces an innovative green ironmaking technology integrated of the direct reduction process and the development and utilization of biomass energy. Biomass was mixed together with iron ore powder and additives for producing green pellets. Hydrogen-rich syngas produced by biomass catalytic gasification was used as a reducing agent, and the heat produced by biomass combustion was used as the heat source of pellet preheating and reduction. Investigations on the effects of preheating, reduction temperature and green pellet size on the quality of direct reduction iron (DRI) show that increasing the preheating and reduction temperature and decreasing the pellet size can improve the quality of DRI. When iron concentrate with the iron grade of 65.21% was taken as raw materials, high-quality DRI with the total iron TFe of 86.1% and the metallization rate of 94.9% can be obtained at optimum operation conditions (pellet size of 8 to 10 mm, preheating at 900℃for 30 min and reduction at 1000℃ for 30 min).
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Key words:
- biomass /
- syngas /
- direct reduction process /
- ironmaking
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