Influencing factors of the reduction of vanadium titano-magnetite carbon composite pellets
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摘要: 通過單因素實驗考察了還原溫度、還原時間及碳氧摩爾比(nC/nO)對釩鈦磁鐵礦含碳球團還原的影響,結合掃描電鏡照片解釋了釩鈦磁鐵礦的還原機理.實驗結果表明,適當升高還原溫度、延長還原時間及增加碳氧摩爾比均可以促進釩鈦磁鐵礦的還原,并且金屬化率隨還原溫度的升高先急劇升高而后趨于平緩,隨著還原時間的延長及碳氧摩爾比的增加而先升高后降低,而殘碳量隨著反應的進行不斷降低.當還原溫度為1350℃,還原時間為30 min,碳氧摩爾比為1.2時,球團的金屬化率達到最大值.通過掃描電鏡照片可以看出,球團在還原過程中形成了鐵連晶,并且在不同的還原條件下鐵連晶的大小及形態不同.Abstract: The influences of reduction temperature,reduction time and the C/O molar ratio on the reduction of vanadium titano-magnetite carbon composite pellets were investigated by single factor experiments.The mechanism of reduction was explained in combination with scanning electron microscopy(SEM).Raising the reduction temperature,prolonging the reduction time and increasing the C/O molar ratio properly can promote the reduction of vanadium titano-magnetite.With the rise of reduction temperature,the metallization rate ascends quickly before 1 350℃ and gently then.With the increase of reduction time and C/O molar ratio,the metallization rate moves up firstly and then down,but the carbon residue content decreases with the reduction proceeding.When the reduction temperature is 1 350℃,the reduction time is 30 min and the C/O molar ratio is 1.2,the metallization rate of the pellets reaches the maximum.SEM observation shows that iron coupling crystals form in the reduction process,and their size and shape vary from each other under different reducing conditions.
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Key words:
- magnetite /
- composite pellets /
- direct reduction /
- metallization
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