Hydrogen absorption behavior of TC4 compacts
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摘要: 利用管式氫處理爐研究了TC4鈦合金壓坯的溫度-平衡氫分壓關系以及吸氫動力學行為,測定了吸氫速率常數和激活能,并分析了吸氫反應各個階段的反應機理.結果表明,隨著吸氫溫度的升高,達到平衡所需要的時間縮短,吸氫后的平衡氫分壓升高.在350℃吸氫時,反應機制分別是形核長大、冪函數定律和三維擴散.在400℃吸氫時,反應機制分別是冪函數定律和三維擴散.在450~750℃吸氫時,反應機制均是三維擴散.TC4鈦合金壓坯吸氫反應的激活能為14.55kJ·mol-1.Abstract: The relation of equilibrium hydrogen pressure with temperature and the hydrogen absorption kinetic behavior of TC4 compacts were investigated with a tubular hydrogen treatment furnace. The rate constant, reaction mechanisms and activation energy of hydrogen absorption at different temperatures were also determined. It is found that the time to reach equilibrium decreases with increasing temperature, but the equilibrium hydrogen pressure increases with increasing temperature. The hydrogen absorption process at 350℃ is controlled by the nucleation and growth, power law and three-dimensional diffusion, the hydrogen absorption process at 400℃ is controlled by the power law and three-dimensional diffusion, while the hydrogen absorption process from 450 to 750℃ is only controlled by the three-dimensional diffusion. The activation energy for hydrogen absorption by TC4 compacts is found to be 14.55 kJ·mol-1.
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Key words:
- titanium alloys /
- hydrogen absorption /
- kinetic behavior /
- reaction mechanism /
- activation energy
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