Electrochemical behavior of various micro-areas on the welded joint of Q235 steel
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摘要: 研究了燃氣舊管道Q235管線鋼焊接接頭各個微觀區域在土壤模擬溶液中的電化學行為.測量了各個微區的極化曲線,測定了相關的電化學參數.結果表明,各區域的Ecorr由低至高和icorr由大至小的順序依次為:熔合線,不完全正火區,過熱區,正火區,回火區,母材,焊縫區.同一個焊接接頭的七個不同熱經歷區域暴露于同一電解質時,也將構成一個多電極體系.其中,熔合線和不完全正火區將成為復雜多電極體系形成的原電池中的陽極,最可能遭受到優先的腐蝕溶解;焊縫區和母材區則是原電池中的陰極,腐蝕敏感性低且在一定程度上受到陰極保護.Abstract: The electrochemical behavior of welded joints of used Q235 pipeline steel was investigated in soil simulation solution. Polarization curves of various micro-areas were measured and related electrochemical parameters were acquired. The results show that the sequence of free corrosion potential from lower to higher or the sequence of free corrosion current density from higher to lower is melt run, incomplete normalized zone, overheated zone, normalized zone, tempered zone, base metal, and weld metal. These micro-areas of a welded joint compose a multiple electrode system when exposed to the same electrolyte. Melt run and incomplete normalized zone suffer corrosion dissolution firstly as the anode of a galvanic cell composed of a complex multiple electrode system, while weld area and base metal are subjected to cathodic protection as the cathode of the galvanic cell.
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