Galvanic corrosion of X70 dissimilar weld joints
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摘要: 利用SEM和光學顯微鏡對X70異種鋼焊接接頭進行顯微組織觀察,并在模擬土壤溶液中測量各區極化曲線以及焊縫和X70鋼以不同面積比偶合時的電偶腐蝕電流.結果表明,該接頭熔合區很窄,無類馬氏體存在,焊縫為細小樹枝晶,Nb和Mo元素嚴重偏析于枝晶間,在實驗溶液中該區呈鈍化狀態,具有優異的耐蝕性.熱影響區粗晶區主要為粗大貝氏鐵素體和分布不均勻的長條狀M-A組元,而X70母材為細小貝氏體組織,二者腐蝕行為無明顯差別,陽極極化電位超過150mV時前者的極化率略高于后者.在焊縫與X70的電偶腐蝕中,陰極反應受氧擴散控制,隨陰/陽極面積比增大,X70腐蝕電流密度急劇增加,具有近似"匯集原理"的腐蝕特點,偶合時焊縫陰極極化電位很高,受到完全保護.Abstract: The microstructures of X70 dissimilar weld joints were studied by optical microscope and SEM. Galvanic corrosion at different area ratios was investigated in simulated soil solution. The results indicated that the fusion zone was so narrow that no martensite-like structure was found. Fine dendrites were obtained in the weld zone, in which Nb and Mo seriously segregated in interdendritic. The corrosion resistance of the weld zone was excellent because of its passive film. There were coarse bainitic ferrite and nonuniformly distributed strip M-A constituent in the coarse-grained heat-affected zone (CGHAZ), and fine bainite existed in X70 base material. Their corrosion behaviors were not obviously different, but as the anode polarized potential exceeded to 150 mV the polarizability of CGHAZ was relatively high. The cathodic reaction rate was dependent on oxygen diffusion when the weld zone was coupled with X70 pipeline steel. The corrosion current density of X70 pipeline steel increased rapidly with increasing area ratio. The corrosion characteristic was similar to "Catchment Principle". Because of high cathodic potential the weld zone did not suffer corrosion.
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Key words:
- X70 pipeline steel /
- dissimilar welding /
- microstructure /
- galvanic corrosion
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