Influence factors of mine gas hydrate formation in surfactant solution containing coal
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摘要: 為促進瓦斯水合物快速生成以預防煤與瓦斯突出,利用可視化實驗系統,進行了14.3~25.4℃和18.66~26.70 Mpa條件下三種含煤表面活性劑溶液體系中瓦斯水合物生成過程的實驗研究,得到了生成過程的p-T-t關系.結合水合物生成速度和含氣率等計算模型對實驗數據進行了計算,并對計算結果和實驗過程進行了分析.結果表明:表面活性劑的加入縮短了水合物生成誘導時間,提高了生成速度和含氣率,合成的水合物樣品含氣率達到136~150;多孔介質(煤)的存在對水合物的生成有較小的延緩;記憶效應對瓦斯水合物生成影響顯著,在擁有水合物分解殘余五面體環等結構的實驗體系中,水合物生成誘導時間縮短10~20倍.Abstract: In order to promote mine gas hydrate formation quickly, which can prevent coal and gas outburst, the processes of gas hydrate formation in three reaction systems containing coal were investigated by utilizing the visible experimental installation under the condition of 14.3-25.4℃ and 18.66-26.70 MPa, and the correlations among pressure, temperature and time were obtained. Experimental data were analyzed based on the computation models of formation rate and volumetric proportion. The results show that the addition of surfactant shortens induction time and improves formation rate and volumetric proportion, and the volumetric proportion of synthetic hydrate samples can amount to 136-150; the existence of porous medium (coal) delays hydrate formation exiguously; the influence of memory effect on gas hydrate formation is notable, the induction time could be shortened by 10-20 times for the experimental system containing residual pentahedral ring structure.
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Key words:
- mine gas /
- hydrate /
- surfactant /
- formation rate /
- memory effect /
- influence factor
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