Precipitates in X70 pipeline steel
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摘要: 用透射電鏡研究了X70針狀鐵素體管線鋼中的析出相.一種是以TiN為主、尺寸較大(50nm~1μm)、外形規則、幾乎呈立方體的Ti (Nb) NC復合析出相,其中Ti/Nb比值處于5~12之間.另一種是以NbC為主、尺寸十分細小(小于20nm)、形態為圓形或橢圓形的Nb (Ti) C復合析出相,Nb/Ti比值處于1~6.37之間,衍射分析結果表明其為多晶粒構成.分析表明,尺寸較大的方形析出相在1150℃的溫度時已經存在,并且在熱模擬過程中變化不大.細小圓形析出相絕大部分是在1100~900℃之間析出,而且與基體保持共格或半共格的關系.V的析出不明顯,其作用相對較弱.高溫熱塑性曲線的測量結果顯示,在沒有變形情況下,1050℃時析出相開始析出,900~850℃之間析出量達到最大.Abstract: The precipitates in X70 acicular ferrite pipeline steel were investigated by transmission electron microscope. There are two typical precipitates in X70 pipeline steel. One is cubic shaped compound precipitates Ti(Nb)NC with the size of 50 nm~1 μm, in which TiN plays the main role and the ratio of Ti/Nb reaches 5~12. The other is spherical shaped Nb(Ti)C with the size less than 20 nm, in which NbC is the main phase with the ratio of Nb/Ti within 1-6.37. The spherical shaped precipitates exist in multigrains proved by electron diffraction. The cubic shaped precipitates formed above 1 150 ℃, and varied scarcely during the process afterwards. The spherical (ellipsoidal) shaped precipitates emerged almost totally in the range of 900 ℃ to 1 100 ℃, and kept coherent or semi-coherent relationship with the matrix. The precipitate of V was not obviously observed reminding the weak effect of V in steel. The results from the high-temperature ductility and strength curves show that the precipitation started at 1 050 ℃ and the amount of the precipitates reach the highest within the temperature range of 900 ℃-50 ℃ in the condition of no deformation.
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Key words:
- X70 pipeline steel /
- acicular ferrite /
- precipitates
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