MgB2 powder synthesized by a self-propagating high-temperature method
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摘要: 利用自蔓延高溫合成法成功制備了MgB2粉末.通過熱力學計算、X射線衍射圖譜分析了各相生成的先后順序及轉化關系,探討了合成反應產物中的相組成、MgB2的分解溫度等.結果表明,自蔓延高溫合成法能制備無MgB4等雜質相的單相MgB2,且晶粒細小易于分解.Abstract: MgB2 powder was successfully synthesized by a self-propagating high-temperature method. Thermodynamic calculation and XRD analysis were used to investigate the powder's synthesizing order and transforming relationship between different Mg-B phases. Phase composition and decomposition temperature in the synthesis process were discussed. The results show that MgB2 phase has synthesized without other impurities such as MgB4. The particle size is small and the MgB2 is easy to decompose.
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