Sintering and mechanical properties of nanoscaled W-40%Cu alloys
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摘要: 以納米W,Cu粉末為原料,通過測定H2中熱壓燒結和無壓燒結的收縮動力學曲線, 研究了納米W-40%Cu化學混合粉末的致密化過程.對比了納米W粉與常規Cu粉(-44μm) 的機械混合粉和納米W-Cu化學混合粉的熱壓燒結致密化過程.測定了燒結合金在300℃和500℃下高溫應力-應變曲線.實驗結果表明:采用納米W-40%Cu化學混合粉末在H2中無壓燒結時最大收縮速率對應溫度為980℃;1200℃燒結平均晶粒小于2μm,相對密度為97%.納米W-Cu化學混合粉在H2熱壓燒結時最大收縮速率對應溫度為930℃;1200℃燒結合金的平均晶粒為0.5μm,相對密度為98%.納米W-Cu化學混合粉熱壓合金高溫抗壓強度比納米W 與常規Cu粉的熱壓合金高.Abstract: The densification of nanoscaled W-Cu powder was investigated through measurements of the shrinkage kinetic curves in hot pressing and hydrogen sintering and compared with that of nanoscaled W powder and traditional Cu powder. The resulted alloys were subjected to hot compression tests at 300℃ and 500℃ to obtain their stress-strain curves. It is indicated that the temperature corresponding to the highest shrinkage rate of nanoscaled W-Cu powder is 980℃ in hydrogen sintering. After sintering at 1200℃, the mean grain size of W phase is less than 2 μm, and the relative density of the alloy is 97%. In hot pressing, however the corresponding temperatures is 930℃. The mean grain size of W phase in the hot pressed alloy from nanoscaled W-Cu powder is 0.5μm at 1 200℃, and its relative density is 98%. The results of hot compression tests at 300℃ and 500℃ showed that the high-temperature strength of the ultrafine grained W-Cu alloy is higher than that of the alloy sintered from nanoscaled W powder and traditional Cu powder.
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Key words:
- W-Cu alloys /
- shrinkage kinetic curve /
- nanometer crystal /
- hot pressing /
- mechanical properties
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