Influence of VC, Cr3C2 on Sintering Properties of Nanocrystalline WC-Co Composite Powders
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摘要: 研究了WC-10Co納米復合粉的熱壓燒結,確定合理的燒結溫度為1360℃.在納米WC-10Co復合粉中分別摻雜1.0%VC和1.0%Cr3C2(質量分數),根據燒結體的斷裂強度、洛氏硬度等性能和斷口形貌,研究了晶粒生長抑制劑VC,Cr3C2對納米復合WC-10Co粉末燒結性能的影響.結果表明,納米WC-10Co復合粉摻雜1.0%VC或1.0%Cr3C2,在1 360℃燒結,可以得到晶粒度小于300nm的整體性能較好的超細WC-Co硬質合金,摻雜1.0%VC抑制晶粒生長的效果要好于摻雜1.0%Cr3C2.Abstract: Nanocrystalline WC-10Co composite powders were sintered by hot-press sintering at 1360℃. The influence of 1.0% VC and 1.0% Cr3C2 (mass fraction) growth inhibitors on the sintering properties of the composite powders was investigated according to the transverse rupture strength (TRS), Rockwell A hardness (HRA) and the scanning electron microscopy (SEM) micrographs of the fractured surfaces of specimens. The result shows that the inhibiting grains growth effect of 1.0% VC is better than that of 1.0% Cr3C2. When nanocrystalline WC-10Co composite powders doped by 1.0%VC or 1.0% Cr3C2 (mass fraction) are sintered at 1360℃, ultrafine WC-10Co cemented carbide with an average grain size of less than 300 nm and better properties are achieved.
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