Microstructures of W-Cu Alloys Prepared by Mechanical Activation Processes
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摘要: 為了改善制備工藝和提高W-Cu合金的密度與性能,對原料粉末進行了機械活化處理,通過成形和燒結制備了W-Cu合金,考察了活化后粉末的變化,觀察了合金的燒結組織并測量了密度.結果表明,機械活化能增大鎢銅粉末的表面能和晶格畸變能,有效地促進燒結,改善燒結組織;燒結體中存在大量團絮狀組織,團粒內部鎢顆粒主要以固相方式燒結在一起,而團粒之間則以液相燒結為主.燒結組織細密、均勻,相對密度達98%以上;燒結組織中鎢銅兩相在微米尺度下仍然結合良好,部分界面出現了互溶.Abstract: W-15%Cu alloys were sintered with mechanically activated powder in order to develop new preparing processes and improve properties of the alloys. The microstructures of activated powder and sintered alloys were observedand its properties such as density were measured. The results show that through mechanical activation, the surface energy and deformation energy of particles increase, and sintering processes were improved. Conglomeration microstructures in the alloys appear, W particles were sintered between each other mainly by way of solid sintering in the conglomerations, and liquid sintering between conglomeration and conglomeration. Microstructure of sintered alloys is compact and homogeneous. The relative density of the alloys is bigger than 98%. W and Cu are well-touched within the micromter scale, and some dissolving happened between the phases.
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Key words:
- powder metallurgy /
- mechanical active /
- W-Cu alloys /
- sintering microstructures
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