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三元系熱力學圖解計算方法——評Darken法與周國治法的內在聯系

謝冬生

謝冬生. 三元系熱力學圖解計算方法——評Darken法與周國治法的內在聯系[J]. 工程科學學報, 1988, 10(2): 226-233. doi: 10.13374/j.issn1001-053x.1988.02.033
引用本文: 謝冬生. 三元系熱力學圖解計算方法——評Darken法與周國治法的內在聯系[J]. 工程科學學報, 1988, 10(2): 226-233. doi: 10.13374/j.issn1001-053x.1988.02.033
Xie Dongsheng. On Graphic Methods for Calculating Thermodynamic Properties of Ternary Systems——Comments on the Inherent Links Between Darken's and Chou's Methed[J]. Chinese Journal of Engineering, 1988, 10(2): 226-233. doi: 10.13374/j.issn1001-053x.1988.02.033
Citation: Xie Dongsheng. On Graphic Methods for Calculating Thermodynamic Properties of Ternary Systems——Comments on the Inherent Links Between Darken's and Chou's Methed[J]. Chinese Journal of Engineering, 1988, 10(2): 226-233. doi: 10.13374/j.issn1001-053x.1988.02.033

三元系熱力學圖解計算方法——評Darken法與周國治法的內在聯系

doi: 10.13374/j.issn1001-053x.1988.02.033

On Graphic Methods for Calculating Thermodynamic Properties of Ternary Systems——Comments on the Inherent Links Between Darken's and Chou's Methed

  • 摘要: 本文系統討論了三元系中由已知一組元活度計算其它組元活度的圖解計算方法,并側重于間接計算方法(${{\rm{\bar G}}_1}-{\rm{\bar G}}$或${\rm{R(R=}}\frac{{\rm{G}}}{{1-{{\rm{x}}_1}}}{\rm{)}} \to {{\rm{\bar G}}_2},{{\rm{\bar G}}_3}$,借助于熱力學基本公式,大大簡化了Darden公式和周國治公式的推導過程,指出兩種方法的內在聯系,給出周國治公式中變量代換R,y的引入思路及意義。經過討論,從理論上證明了周國治法實際上是Darken法的發展和完善,是三元系熱力學計算的好方法。本文還提出兩個有用的判別式,可由有關二元系的熱力學數據分別對三元系實驗結果和圖解計算結果加以檢驗,使計算方法更加完善。

     

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  • 收稿日期:  1986-11-04
  • 網絡出版日期:  2021-11-15

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