The Microstructure of Scale for Corrosion Resistant Steel
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摘要: 本文探討了耐蝕鋼的氧化皮物相組成、顯微結構與鋼耐蝕性的關系。冷軋板氧化皮的物相組成為纖鐵礦、非晶質氫氧化鐵以及金屬鐵顆粒。耐蝕性好的鋼,纖鐵礦發育,“港灣狀”銹蝕現象少;反之則以非晶質氫氧化鐵為主,氧化皮中金屬顆粒也較多。熱軋板除上述物相外,主要為磁鐵礦與赤鐵礦。各物相有分帶現象。磁鐵礦帶發育、氧化皮與金屬呈鋸齒狀鑲嵌者耐蝕性好。
加有稀土元素的熱軋板,稀土元素能凈化鋼質、球化夾雜物,也能抑制氧化皮中磁鐵礦等在水、氣下的分解作用,有利于提高鋼的耐大氣腐蝕。Abstract: The relation between atmospheric corrosion resistance and the composition and microstructure of scales of weathering steel is discussed The scale of cold-rolled plates consists of lepidocrocites,iron hydroxides and dispersed iron particles. Comparing with that of carbon steel, the atmospheric resistance of weathering steel is very good, as lepidocrocites grow just adjacent to iron matrix. For the scales of carbon steel the iron matrix was not protected fron atmospheric corrosion for iron hydroxide was made as "harbour" between scale and metal. Magnetites and hematites were formed on the surface of hot-rolled plates.
The scale with developed magnetite and a sawtooth structure connected with matrix coule provide a good protection to the matrix.The rare earth added made the steel cleaner and inclusions more g ranular. It seems that rare earth in the steel inhibited the decomposition of magnetite under the reaction with water and air. The steel treated by rare earth had better atmospheric corrosion resistance.-
Key words:
- corrosion-resistance steel /
- scale /
- the composition of minerals /
- microstructure
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