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EXAFS的分辨率和信噪比與實驗參數間相互關聯的探討

劉建民 趙伯麟 陳訓平 吳平

劉建民, 趙伯麟, 陳訓平, 吳平. EXAFS的分辨率和信噪比與實驗參數間相互關聯的探討[J]. 工程科學學報, 1983, 5(2): 102-112. doi: 10.13374/j.issn1001-053x.1983.02.029
引用本文: 劉建民, 趙伯麟, 陳訓平, 吳平. EXAFS的分辨率和信噪比與實驗參數間相互關聯的探討[J]. 工程科學學報, 1983, 5(2): 102-112. doi: 10.13374/j.issn1001-053x.1983.02.029
Liu Jianmin, Zhao Bolin, Chen Xunping, Wu Ping. A Study of the Relationship Between the Resolution Signal to Noise Ratio and the Experimental Data of EXAFS[J]. Chinese Journal of Engineering, 1983, 5(2): 102-112. doi: 10.13374/j.issn1001-053x.1983.02.029
Citation: Liu Jianmin, Zhao Bolin, Chen Xunping, Wu Ping. A Study of the Relationship Between the Resolution Signal to Noise Ratio and the Experimental Data of EXAFS[J]. Chinese Journal of Engineering, 1983, 5(2): 102-112. doi: 10.13374/j.issn1001-053x.1983.02.029

EXAFS的分辨率和信噪比與實驗參數間相互關聯的探討

doi: 10.13374/j.issn1001-053x.1983.02.029

A Study of the Relationship Between the Resolution Signal to Noise Ratio and the Experimental Data of EXAFS

  • 摘要: 本文詳細討論了EXAFS測定的分辨本領、信噪比與實驗參數間的相互關聯;提出了實驗參數臨界條件的概念及其確定的方法;在臨界條件下分別討論了分辨本領、信噪比與臨界實驗參數值的相互關系并由此導出如下結論:1.當入射狹縫,出射狹縫寬度均為臨界參數時,EXAFS測定的分辨本領與分光晶體擺動曲線的寬度無關,而信噪比則取決于分光晶體擺動曲線寬度所表征的嵌鑲塊大小對強度分布和消光效應的影響。2.當接收狹縫,分光晶體擺動曲線的寬度均為臨界參數時,入射狹縫可增至最佳寬度,其分辨本領不僅保持不變,還能顯著提高信噪比。當入射狹縫繼續增大,超過最佳寬度時,信噪比不再增加。文中由此指出:當所用分光晶體完整性欠佳時,以采用結論1的條件為宜;當分光晶體完整性較好則應采用用結論2所提出的條件。

     

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