鋼包工作襯用耐火材料的研究現狀及最新進展

王恩會; 陳俊紅; 侯新梅

doi:10.13374/j.issn2095-9389.2019.06.001

鋼包工作襯用耐火材料的研究現狀及最新進展

doi: 10.13374/j.issn2095-9389.2019.06.001

1.
北京科技大學鋼鐵共性技術協同創新中心, 北京 100083
2.
北京科技大學材料科學與工程學院, 北京 100083

基金項目:

國家自然科學基金資助項目 51874027

國家自然科學基金資助項目 U1460201

中央高校基本科研業務費資助項目 FRF-TP-15-006C1

國家優秀青年基金資助項目 FRF-TP-15-006C1

詳細信息

通訊作者:
侯新梅, E-mail: houxinmei01@126.com

中圖分類號: TG142.71
計量
- 文章訪問數: 1293
- HTML全文瀏覽量: 586
- PDF下載量: 84
- 被引次數: 0
出版歷程
- 收稿日期: 2018-10-06
- 刊出日期: 2019-06-01

Current research and latest developments on refractories used as ladle linings

1.
Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China
2.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

More Information

Corresponding author: HOU Xin-mei, E-mail: houxinmei01@126.com

摘要

摘要: 綜述了近年來鋼包工作襯用耐火材料的研究現狀及最新進展, 尤其對傳統鋼包工作襯用耐火材料的應用背景及存在問題進行了分析和匯總.在此基礎上, 進一步提出了適用于超低氧鋼(或潔凈鋼)冶煉用耐火材料的研發方向, 即通過耐火原料組分選擇和結構匹配設計, 實現對耐火材料性能的精確控制.新型鋼包工作襯用耐火材料需兼顧優異熱機械性能的同時, 還應具備鋼水凈化的功能.
- 耐火材料 /
- 鋼包工作襯 /
- 夾雜物 /
- 組分選擇 /
- 結構設計
Abstract: Non-metallic inclusions significantly influence the properties of steels. Take heavy rail steel as an example, Al₂O₃ inclusions can become fatigue source under cyclic stress, resulting in the rupture of the steel. Existing technologies and equipment can effectively reduce the amount and harm brought about by such inclusions, but they cannot guarantee the complete removal of large-sized and high-melting-temperature inclusions. Large-sized non-metallic inclusions give rise to instability in high-quality steels; as such, they are one of the bottlenecks in the development of steel. In the steel-making process, refractories in close contact with molten steel are a main source of large-sized non-metallic inclusions. Therefore, adopting appropriate ladle-lining refractories for refining and alloying is vital. This paper summarized the current research and latest developments in refractories used as ladle linings, and analyzed the application background and existing problems of traditional ladle lining refractories. Based on this discussion, future research directions regarding refractories suitable for the smelting of ultra-low-oxygen steel (or clean steel) as well as approaches to precisely control refractory properties via the reasonable selection of material components and structures were then provided. Novel ladle-lining refractories must possess not only excellent thermomechanical properties but also the ability to purify molten steel.
- refractory /
- ladle lining /
- inclusions /
- component selection /
- microstructure design

HTML全文

圖 1 LF精煉過程鋼中夾雜物組成變化^[3]. (a) 精煉開始; (b) 精煉26 min; (c) 精煉147 min^[3]

Figure 1. Change in inclusion composition in the LF refining process^[3]: (a) onset of refining, (b) refining for 26 min; (c) refining for 147 min^[3]

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圖 2 LF精煉后期典型夾雜物的掃描電鏡-能譜線掃描照片^[3]

Figure 2. SEM-EDS scans of typical inclusions found at later stages of the LF refining process^[3]

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圖 3 1200 (a) 和1500℃ (b) 反應3 h添加Al的試樣電鏡圖^[29]

Figure 3. Back-scattered electron images of Al-added samples after treatment for 3 h at 1200 (a) and 1500℃ (b)^[29]

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圖 4 1200 (a) 和1500℃ (b) 反應3 h添加Si的試樣電鏡圖^[29]

Figure 4. Back-scattered electron images of Si-added samples after treatment for 3 h at 1200 (a) and 1500℃ (b)^[29]

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圖 5 添加/不添加3%質量分數抗氧化劑的鎂碳磚在1300℃氧化6 h后的氧化形貌^[30]

Figure 5. Oxidized areas of Mg O-C specimens with/without 3%mass fraction of antioxidant after 6 h of oxidation at 1300℃^[30]

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圖 6 1900℃合成的Al₄SiC₄晶體的掃描電鏡照片^[35]

Figure 6. SEM images of Al₄SiC₄crystals synthesized at 1900℃^[35]

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圖 7 1450℃高溫抗折試驗后試樣斷口的顯微形貌^[52]. (a) 無ZrO₂添加試樣; (b) 9%質量分數ZrO₂微粉添加試樣^[52]

Figure 7. Fracture micrographs of specimens after rupture testing at 1450℃^[52]: (a) sample without ZrO₂addition; (b) sample with 9%ZrO₂addi-tion^[52]

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圖 8 CM₂A₈抗渣侵蝕后的掃描電鏡照片^[74]

Figure 8. SEM images of the crucible after slag resistance testing^[74]

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