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CO2–工業廢渣協同固化渣土多尺度試驗研究

Multi-scale experimental study on the waste soil co-solidified by CO2 and industrial waste

  • 摘要: 為實現工程渣土的高效固化并資源化利用,以純工業廢渣—WZ01為主固化劑,電石渣(CCR)為堿性激發劑,結合CO2碳化技術,采用微觀–單元體–模型多尺度試驗研究CO2–CCR–WZ01協同固化渣土的可行性,通過開展無側限抗壓強度試驗與CO2吸收率測定試驗來分析通碳時間(Tc)、碳化溫度(Kc)、通碳壓強(Pc)、CO2濃度(Wc)四種因素對碳化效果的影響規律,并結合微觀與模型試驗探究CO2–WZ01–CCR固化土的微觀演變規律,從多尺度角度評價CO2–CCR–WZ01協同固化技術的固化效果。結果表明:在Tc=6 h、Kc=60 ℃、Pc=600 kPa、Wc=50%時,渣土的碳化效果最佳;在碳化–固化反應的內外協同作用下,生成的方解石、C–A–H、C–S–H等產物可以有效填充孔隙,提高渣土強度;CO2–CCR–WZ01協同作用下碳化土的貫入指數最低,承載力達到700 kPa,土體物理力學性質得到顯著提升。CO2–WZ01–CCR協同固化技術具有高效、低碳、環保等特征,可在渣土資源化利用中得到廣泛引用。

     

    Abstract: The feasibility of CO2–CCR–WZ01 co-curing of engineering residues was investigated through multi-scale tests, including micro-, elementary-, and model-scale experiments to enhance the efficiency of curing and resource utilization of engineering waste soil. Pure industrial waste slag (WZ01) was used as a curing agent, while calcium carbide residue (CCR) served as an alkaline activator, in combination with CO2 carbonation technology. Unconfined compressive strength tests and CO2 absorption rate tests were conducted to analyze the effects of four factors on the carbonation process: carbonation time (Tc), carbonation temperature (Kc), carbon pressure (Pc), and CO? concentration (Wc). The microscopic evolution of CO2–CCR–WZ01-stabilized soil was examined through microscopic and model tests to assess the effectiveness of the CO2–CCR–WZ01 co-curing technology. The results indicate optimal carbonation occurs when Tc = 6 h, Kc = 60 °C, Pc = 600 kPa, and Wc = 50%. The synergistic effect of the carbonation-curing reaction promotes the formation of products such as calcite, C–A–H, and C–S–H, which effectively fill the pores and enhance the strength of the residual soil. Under the influence of CO2–CCR–WZ01, the permeability index of the carbonized soil is significantly reduced, the bearing capacity reaches 700 kPa, and substantial improvements are observed in the basic physical properties of the soil. The CO2–CCR–WZ01 co-curing technology demonstrates high efficiency, low carbon emissions, and environmental sustainability, making it a promising solution for the resource utilization of engineering residues.

     

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