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碳化物基復合材料在電磁波吸收應用中的研究進展

Research progress on carbide-based composites for electromagnetic wave absorption applications

  • 摘要: 電磁波吸收材料在過去幾十年中取得了長足的進步,由于其對入射電磁波的重要衰減作用,在防輻射和反雷達探測中發揮著越來越重要的作用. 隨著納米技術的蓬勃發展,高性能電磁波吸收材料的設計已不僅僅依賴于單一成分介質的固有特性,而是更加注重不同成分的協同效應,從而產生豐富的損耗機制. 在各種候選材料中,碳化物通常具有化學穩定性、低密度、可調介電性能和多樣化的形態/微結構等特點,因此,探索并設計碳化物基復合材料將是獲得具有良好實際應用前景的新型電磁波吸收材料的可行途徑. 本文介紹了與介電復合材料相關的電磁損耗機制,然后重點介紹碳化物基復合材料作為高性能電磁波吸收材料的最新進展,包括共價型碳化物、間充型碳化物、MXene基碳化物以及一些不常見的碳化物基復合材料和多組分復合材料. 詳細討論了有關成分優化、結構工程、性能增強和結構?功能關系的關鍵信息. 此外,在比較了一些代表性復合材料的性能后,還提出了碳化物基復合材料發展面臨的一些挑戰和前景.

     

    Abstract: With continuously evolving wireless communication technologies, the technological revolution marked by advances in artificial intelligence, the Internet of Things, and the metaverse is fundamentally reshaping our society, making it more convenient, intelligent, and information-centric. However, owing to the booming development and popularization of 5G and mankind’s over-reliance on a variety of smart devices, electromagnetic waves have permeated every aspect of people’s lives. This has led to an alarming increase in the density of electromagnetic radiation and electromagnetic pollution. Electromagnetic absorption materials are functional materials that efficiently absorb incident electromagnetic waves and convert microwave energy into Joule heat to process external electromagnetic waves, thereby regulating them. Over the last few decades, electromagnetic wave-absorbing materials have made significant strides and are playing increasingly crucial roles in radiation protection and antiradar detection, owing to their effective attenuation of incident electromagnetic waves. With the vigorous development of nanotechnology, the design of high-performance electromagnetic wave-absorbing materials has relied on the intrinsic properties of single-component media and has focused on the synergistic effect of different components, resulting in rich loss mechanisms. In recent years, carbide-based composites have received increasing attention in the field of electromagnetic absorption. Among the various candidate materials, carbides are typically characterized by chemical stability, low density, tunable dielectric properties, and diverse morphologies/microstructures. Therefore, exploring and designing carbide-based composites is a feasible approach for the development of novel electromagnetic wave-absorbing materials with promising prospects for practical applications. A summary of the status of the development of carbide-based composites as a new generation of electromagnetic wave-absorbing materials would be helpful for understanding and furthering their advancement. In this review, we introduce the electromagnetic loss mechanisms associated with dielectric composites and discuss the recent advances in the use of various types of carbide-based composites as high-performance electromagnetic wave-absorbing materials. These composites include covalent carbides, interstitial carbides, less common carbide-based composites, and multicomponent composites, such as MXene and high-entropy MAX phase carbides. Key information on composition optimization, structural engineering, performance enhancement, and structure–function relationships are discussed. Additionally, the properties of representative composites are compared, and the challenges and prospects associated with the development of carbide-based composites are presented.

     

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