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甲烷干重整與二氧化碳甲烷化的工藝耦合研究

Study on process coupling between dry reforming of methane and methanation of carbon dioxide

  • 摘要: 甲烷干重整(DRM)與二氧化碳甲烷化(MCD)過程均具有較強的二氧化碳消納效應,但其單獨運行時需要分別消耗大量天然氣與氫氣,且二者能耗均較高,從而制約了兩個工藝的發展與應用,因此探索研究該問題的解決方案對于低碳發展具有重要意義. 本文分析了甲烷干重整與二氧化碳甲烷化兩個獨立工藝的特點,基于兩個反應體系的原料與產物之間可互為利用及二者反應熱效應可相互補償的條件性,初步判斷DRM與MCD工藝之間存在質量耦合與熱量耦合的可能性. 據此,首次創新性地設計了DRM?MCD可能的工藝耦合方案,從流程模擬角度證實了工藝耦合的可行性,并分析了不同情形下的耦合特性. 結果表明,隨著催化劑技術的發展與進步,DRM與MCD工藝之間可以實現質量、能量的高效雙重耦合,耦合工藝具備可顯著降低天然氣、氫氣消耗以及大幅節能降耗的效果,并具有優良的二氧化碳消減與資源化利用效應,且耦合工藝具有靈活的可調節性. 研究結果可為DRM與MCD工藝耦合方案的設計與優化,以及未來該耦合工藝潛在的工程應用價值與可行性研究提供可參考的基礎.

     

    Abstract: Both dry reforming of methane (DRM) and methanation of carbon dioxide (MCD) processes offer impressive capabilities for carbon dioxide utilization. However, operating these processes independently involves substantial consumption of natural gas and hydrogen, along with high energy demands, which restrict their broader application. Addressing these challenges is crucial for advancing low-carbon development. This work analyzes the characteristics of two independent processes, namely DRM and MCD. It explores the potential for mass and heat coupling between them, considering the complementary nature of their feedstocks, products, and thermal effects. This investigation leads to the innovative proposal of process coupling schemes for DRM and MCD, marking a pioneering step in this research area. The feasibility of such coupling is assessed through process simulations, examining the characteristics under different situations. The results show that advancements in catalyst technology could enable efficient dual coupling of the DRM and MCD processes in terms of both quality and energy. This coupling process significantly reduces the consumption of natural gas and hydrogen, offering substantial energy savings. In addition, it demonstrates excellent carbon dioxide elimination and utilization capabilities, with the added benefit of flexible adjustability. A key highlight of the DRM?MCD coupling process is its high mass integration efficiency. Methane produced in the MCD process can serve as a feedstock for DRM, addressing natural gas shortages. Similarly, hydrogen generated by DRM can feed into the MCD, potentially reducing hydrogen usage by at least 26% and mitigating hydrogen resource constraints. Moreover, the coupled process has excellent energy integration. The heat from the exothermic MCD system can be transferred to the endothermic DRM system, leading to significant reductions in energy consumption. When compared to operating the DRM and MCD processes separately, the coupled process could lower total energy consumption by at least 44% and 28%, respectively. This work provides valuable insights for the design and optimization of DRM and MCD process coupling. It underscores the potential engineering applications and feasibility of this approach, contributing to the goal of achieving carbon neutrality by transforming conventional energy and chemical processes.

     

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