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低碳鋼中高密度超細納米第二相粒子的快速獲取

Acquiring high density of ultrafine second-phase nanoparticles quickly in low-carbon steel

  • 摘要: 一般熔煉過程中,非金屬化合物以夾雜物的形式存在,對鋼的力學性能和壽命都會有損害. 當夾雜物尺寸小到納米量級,從而在鋼中形成高密度分布的納米第二相顆粒卻能夠有效同時提升鋼的強度和韌性. 本文通過在熔煉過程中施加動態磁場,制備了Fe–0.04C–1.5Mn–0.5Ti–0.5Al2O3(Fe–TAMO)鋼,然后通過軋制和退火處理實現對Fe–TAMO鋼的晶粒尺寸優化和等軸化. 透射電鏡觀察發現鑄態組織中彌散分布著納米第二相粒子,密度為3.3×1015 m?2,顆粒的平均直徑為2.75±0.803 nm. 通過EDS能譜分析,第二相顆粒為Ti–Al–Mn氧化物. 利用萬能試驗機分別測試了鑄態、軋制態以及退火態Fe–TAMO鋼的壓縮力學性能,鑄態Fe–TAMO鋼的晶粒尺寸為143 μm,抗壓屈服強度為150 MPa,約為鑄態純鐵素體鋼的2倍. 經過軋制和退火處理,Fe–TAMO鋼的晶粒尺寸減小為64 μm,抗壓屈服強度為334 MPa. 該方法極大簡化了工藝流程,實現了在短時間(約3 min)內將超細的納米第二相粒子均勻分散在鋼基體中,密集分布的第二相納米顆粒有效提高了鋼的強度,并且通過后續熱處理能進一步提升鋼的力學性能,為大批量生產高性能鋼提供了一個新思路.

     

    Abstract: In the general smelting process, nonmetallic compounds manifest as inclusions. These inclusions, typically larger than 5 μm, can significantly reduce the strength, toughness, and processability of steel. More critically, they pose a threat to the service life of steel. To mitigate these adverse effects, the practice of inclusion modification has been developed. Typically, calcium and magnesium elements are employed for this purpose. However, despite these efforts, the size of modified inclusions often remains at the micron level. Although there is some improvement in mechanical properties, the presence of these inclusions still compromises the steel matrix. Therefore, controlling the size, quantity, and distribution of nonmetallic inclusions during steel manufacturing becomes imperative. When inclusions are reduced to nanometer size, the formation of a high density of nanosized second-phase particles can substantially improve the strength and toughness of the steel. In this study, we prepared Fe–0.04C–1.5Mn–0.5Ti–0.5Al2O3 (Fe–TAMO) steel by applying a dynamic magnetic field during the smelting process. This was followed by grain size optimization and equiaxed optimization through rolling and annealing processes. Transmission electron microscopy revealed that the second-phase particles were uniformly dispersed within the as-cast Fe–TAMO steel matrix. The density of these particles reached 3.3 × 1015 m?2, with an average diameter of 2.75 ± 0.803 nm. Energy-dispersive x-ray spectroscopy analysis identified these particles as oxides of Ti–Al–Mn. The compressive mechanical properties of Fe–TAMO steel, in its as-cast, as-rolled, and as-annealed states, were evaluated using a universal testing machine. The grain size of the as-cast Fe–TAMO steel is 143 μm, with a compressive yield strength of 150 MPa, approximately double that of as-cast pure ferritic steel. After rolling, the grain size decreased to 119 μm, and the compressive yield strength increased to 484 MPa. Following annealing, the grain size was further reduced to 64 μm, with a compressive yield strength of 334 MPa. These results demonstrate that the applied method effectively minimizes the size of the second-phase particles, with most controlled within 5 nm. The densely distributed second-phase nanoparticles significantly improve the steel strength, while subsequent heat treatments allow for adjustments in grain size to further enhance mechanical properties. This method streamlines the process flow to a single step, achieving uniform dispersion of ultrafine nanosized second-phase particles in the steel matrix in about a mere 3 minutes. Moreover, it holds great potential for industrial production, offering a new avenue for the mass production of high-performance steel.

     

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