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汽車用齒輪鋼奧氏體晶粒長大與第二相粒子控制技術研究進展

Research progress on austenite grain growth and second-phase particle control technology in automotive gear steel

  • 摘要: 伴隨著全球雙碳政策的實施,節能減排成為汽車制造業發展的首要目標之一. 汽車用齒輪鋼采用的更高溫度結合更短時間的滲碳工藝是目前各齒輪生產企業最為直接的降碳措施,但齒輪鋼在高溫滲碳生產過程中卻時常發生奧氏體晶粒異常粗大的問題,且滲碳溫度越高混晶現象越嚴重. 因此,各企業對齒輪鋼進行微合金化,通過添加微合金元素在加熱過程中析出第二相粒子產生釘扎作用來阻礙奧氏體晶粒異常長大,從而需要對復雜的齒輪鋼奧氏體晶粒長大與第二相粒子析出機制進行研究. 通過對奧氏體晶粒度、奧氏體晶粒長大機制及模型、第二相粒子(Nb(C,N)/AlN)對奧氏體晶界移動的釘扎作用及模型、以及加熱溫度與保溫時間對奧氏體晶粒長大和第二相粒子釘扎作用的影響等進行了文獻綜述,闡明了奧氏體晶粒長大規律、第二相粒子的控制方法與抑制奧氏體晶粒長大的釘扎機制,為高質量齒輪鋼的生產提供參考.

     

    Abstract: With the implementation of the global two-carbon policy, energy saving and CO2 emission reduction have become important developmental goals of the automobile manufacturing industry. At present, the combination of high temperature for the automobile gear steel and short carburizing time is the most direct carbon reduction countermeasure for gear production enterprises. However, the problem of abnormally coarsened austenite grains often occurs in the high-temperature carburization of gear steel. With the increase in carburizing temperature, the degree of mixing crystals becomes serious. As a requirement of gear manufacturing enterprises, microalloying is carried out on the carburized gear steel. Upon the addition of microalloying elements, the second-phase particles are precipitated during heating, and the pinning effect is generated to prevent the movement of austenite grain boundaries, thus preventing the abnormal growth of austenite grains. Although the second-phase particles precipitate at the usual carburizing temperature, the partial solid solution of particles appears. In this work, the effects of the heating temperature and holding time on the austenite grain size of gear steel are studied to clarify the mechanisms of complex austenite grain growth and second-phase particle precipitation for the realization of fine austenite grain size after high-temperature carburization. The influence of the contents of microalloying elements (Nb, Al) on the pinning effect, precipitation position, and solution temperature of the second-phase particles (Nb (C, N)/AlN) are also discussed. Austenite grain growth models, critical sizes of austenite grain abnormal growth, and pinning force models of second-phase particles are summarized. The austenite grain growth model is based on the Beck equation, and the most common models are the modified Sellars and Arrhenius models. For the study of the inhibition effect on austenite grains, the pinning force model is used to study the critical size of austenite by modifying the dimensionless constant (A) of the Zener equation mainly through the pinning effect (Pz) produced by all particles on the grain boundary. After the experimental data are obtained, the trend of austenite growth can be predicted accurately by fitting the curve using the mathematical method. The precipitated second-phase particles are generally distributed along the grain boundary. Nb (C, N) particles have a higher solution temperature than AlN particles, so they are more stable at high temperatures. When the temperature exceeds the grain coarsening temperature, the precipitated particles become dissolved or coarsened. The mixed crystal structure generally starts to appear at about 1000 ℃, and adding the appropriate amount of microalloying elements can increase the coarsening temperature.

     

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