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燒結礦堿度對綜合爐料交互反應的影響

Effect of sinter basicity on the interactive reaction of composite burdens

  • 摘要: 以不同堿度的燒結礦及燒結礦與塊礦的混合礦為研究對象,利用荷重軟化熔滴裝置,考察了燒結礦堿度對綜合爐料軟熔性能及不同爐料間交互作用的影響。研究發現:隨著燒結礦堿度增加,爐料結構中塊礦的質量配加比例提高,爐料間的交互作用增強,主要表現為綜合爐料軟化開始溫度及熔融開始溫度降低,混合爐料的透氣性得到改善。爐料結構的變化使礦物間的交互反應隨著燒結礦堿度的提高而增強,進而導致液相成分發生改變,降低了初渣物相熔點,而燒結礦堿度過高時會惡化料柱的透氣性。同時通過掃描電子顯微鏡?能量色散譜儀(SEM?EDS)及X射線衍射(XRD)精修表征整個還原過程燒結礦物相變化,渣相中主要物相為浮氏體和硅酸鈣,隨著燒結礦堿度增加,在不同斷點2CaO·SiO2的含量呈現降低趨勢,表明燒結礦還原過程生成的高熔點物相隨之降低,綜合爐料的液相生成溫度隨之降低,爐料間交互作用增強。因此,適當提高燒結礦堿度,提高塊礦入爐的質量配比,利于高爐的強化冶煉。

     

    Abstract: With the deepening of the concept of interactive reaction and the development of several studies, metallurgists are no longer simply concerned with the metallurgical properties of a single charge. Instead, they comprehensively consider the interactive reaction of composite burdens. The interactive reaction is mainly affected by the chemical composition, microstructure, reduction temperature, and other factors of the ferrous burdens. In this study, taking a sinter with different basicities and a mixed ore of sinter and lump as the research object, the effect of sinter basicity on the smelting and dripping paraments of a composite burden and the interactive reaction between different burdens was investigated using melting–dripping equipment. The results show that the dripping temperature of a single sinter increases with sinter basicity. In the integrated burdens protocol, the proportion of lump ore increased, and the interaction between the burdens was enhanced, which is mainly manifested as a reduced softening start temperature and melting start temperature of the composite burden. The air permeability of the mixed charge was improved. A change of burden structure enhances the interaction between minerals with increasing sinter basicity, resulting in a change in the liquid phase composition, which reduces the melting point of the primary slag phase, and when the basicity of the sintered is too high, it will deteriorate the gas permeability of the material column. This result is not conducive to the intensive smelting of blast furnaces. At the same time, the sintered mineral phase changes throughout the reduction process were characterized using SEM-EDS and XRD, and the main phases in the slag phase are wustite and calcium silicate. The interactive reaction between the sinter and lump produces low melting point materials, which is verified by calculating the phase diagram of CaO–SiO2–FeO. With increasing sinter basicity, the content of 2CaO·SiO2 at different breakpoints decreased. This result shows that the high melting point phase formed during the reduction process of the sinter decreases, the liquid phase formation temperature of the composite burden decreases, and the interaction between the burdens increases. Therefore, appropriately increasing the sinter basicity and increasing the lump ore proportion benefits the enhanced smelting of a blast furnace. The theoretical and experimental results obtained in this research are of great importance for improving the production application of the proportion of lump in the furnace and developing efficient and low-carbon ironmaking.

     

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