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三維導電載體應用于鈉金屬負極的研究進展

Progress of 3D conductive framework for Na metal anode

  • 摘要: 鈉金屬因其成本低、自然豐度高、氧化還原電位低和理論比容量高等優點,被認為是高能電池的理想負極材料。然而,鈉金屬在充放電過程中易發生體積膨脹和產生鈉枝晶,導致電池性能不斷惡化,并引發安全隱患,嚴重阻礙了鈉金屬電池在實際中的應用。為了解決上述問題,國內外已進行了大量探索。其中,構建三維導電載體可以有效降低局部電流密度和成核能,抑制枝晶生長和減緩體積膨脹,在未來應用方面具有巨大的潛力。本文綜述了近年來利用三維導電載體來提高鈉金屬負極電化學循環穩定性的研究進展并對三維導電載體進行了總結和分類。最后,從基礎研究和實際應用兩個方面討論了三維導電載體材料在鈉金屬負極中的發展前景和未來研究方向。

     

    Abstract: Sodium is considered an ideal anode material for high-energy batteries because of its low cost, high natural abundance, low redox potential (?2.71 V vs SHE), and high theoretical specific capacity (1166 mA·h·g?1). However, due to the high reactivity, sodium rapidly reacts with the electrolyte to form an unstable solid electrolyte interface (SEI) layer during stripping/plating cycling. In addition, due to the large size change of sodium, the SEI layer repeatedly breaks and reassembles, resulting in the continuous consumption of sodium and electrolyte, as well as low coulombic efficiency and rapid capacity loss. Simultaneously, due to an uneven electric field distribution on sodium, numerous sodium dendrites generate during the repeated plating/stripping cycles. The growing Na dendrites easily pierce the separator, causing a short circuit and a series of safety issues. The above issues lead to the deterioration of battery performance and safety risks, thus considerably hindering the application of sodium metal batteries. Various studies have been conducted to solve these issues, including electrolyte engineering, artificial SEI layers, current collector and interlayer engineering, solid-state electrolyte engineering, and three-dimensional (3D) frameworks for sodium metal. Among various improvement strategies, the construction of a 3D conductive framework can effectively reduce the local current density, decrease nuclear energy, inhibit Na dendrite growth, and impede volume expansion, thus having a great potential in future applications. In this study, the current research progress in using various 3D conductive frameworks to improve the cycling stability of a sodium metal battery is reviewed, including carbon-based, metal-based, and MXene-based frameworks. Simultaneously, the pros and cons of different 3D conductive framework technologies in recent years are summarized and classified, and the electrochemical performance parameters of different 3D conductive frameworks for sodium metal batteries are compared. Finally, the development prospect and direction of 3D conductive frameworks in sodium metal anodes are discussed from basic research and practical applications. This review provides deeper insights into building more comprehensive and efficient sodium metal anodes. The 3D conductive framework technology can remarkably improve the cycle life and safety of a sodium metal battery. Multistrategy joint research methods will facilitate the practical applications of a sodium metal battery. Further exploration of the deposition behavior of sodium metal is required in the future, and we believe that it can definitely achieve commercial applications with continuous efforts.

     

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