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62Sn36Pb2Ag組裝焊點長期貯存界面化合物生長動力學及壽命預測

Long-term storage life prediction and growth kinetics of intermetallic compounds in 62Sn36Pb2Ag solder joints

  • 摘要: Sn基合金焊接接頭是電子產品不可或缺的關鍵部位,是實現電子元器件功能化的基礎,電子整機失效往往由于焊點的損傷所導致,焊點的壽命預測對電子產品的可靠性研究具有重要意義。金屬間化合物(IMC)厚度是衡量焊點質量的重要參數,以IMC層厚度為關鍵性能退化參數,以62Sn36Pb2Ag組裝的小型方塊平面封裝(QFP)器件焊點為研究對象,采用掃描電子顯微鏡對在94、120和150 °C三種溫度貯存不同時間后的焊點微觀形貌進行表征,測量了IMC層的厚度,基于阿倫尼烏斯方程建立了雙側界面金屬間化合物生長動力學模型。并以其作為關鍵性能退化函數,通過對初始IMC厚度進行正態分布擬合獲得失效密度函數,進而獲得可靠度函數對焊點的長期貯存失效壽命進行了預測。研究結果有望對長期貯存焊點的壽命預測方式提供新的思路,為62Sn36Pb2Ag釬料的可靠應用提供試驗和數據支撐。

     

    Abstract: Tin-based alloy solder joints are an indispensable key part of electronic products and the basis of realizing the functionalization of electronic components. The failure of an electronic product is often caused by solder joint damage. Life prediction of the solder joint is of great significance for the reliability research of electronic products. The intermetallic compound (IMC) thickness is an important parameter to evaluate the quality of solder joints. This study takes the thickness of the IMC layer and the assembly solder joints of the 62Sn36Pb2Ag QFP device as the key performance degradation parameter and the research object, respectively. After the reflowing process, Cu6Sn5 and Cu3Sn IMC phases were observed at the copper lead side, and the (CuxNi1-x)6Sn5 phase was observed at the PCB side. The evolution of interfacial microstructures was observed by a scanning electron microscope (SEM). The thickness of the IMC layer after storage at 94, 120, and 150 °C for different periods (1, 4, 9, 16, 25, 36, 49 days) was monitored. The growth process of the IMC is controlled by diffusion. As the storage time increases, the thickness of the IMC layer gradually increases. The growth rate of the IMC layer increases with the increase of the storage temperature because of the higher diffusion coefficient. Based on the Arrhenius equation, the growth kinetics model of the IMC with a bilateral interface is established. The failure density function is obtained by fitting the initial IMC thickness with a normal distribution, and the reliability function is then obtained to predict the long-term storage failure life of QFP assembly solder joints. Finally, this work calculates the median life and characteristic life of QFP assembly solder joints to be 16092 years and 17471 years, respectively. These results are expected to provide a new way to predict the life of solder joints stored for a long time and provide experimental and data support for the reliable application of the 62Sn36Pb2Ag solder.

     

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