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鐵酸鋅碳熱還原動力學及反應機理

Kinetics and reduction mechanism of non-isothermal analysis carbothermal reduction of zinc ferrite

  • 摘要: 對鐵酸鋅非等溫碳熱還原反應動力學及其還原反應機理進行了研究。通過不同溫度條件下還原后的鐵酸鋅團塊物相分析(XRD)對其碳熱還原的物相轉變過程進行了解析,950 ℃時出現FeO0.85·xZnO無定型物質,此時Fe3+被還原成Fe2+。探討了鐵酸鋅碳熱還原過程轉化率與轉化速率的關系,該還原過程可以劃分為三個階段,第二階段的轉化率變化最大(0.085~0.813)。最后,通過等轉化率法和主曲線擬合法對不同升溫速率條件下鐵酸鋅碳熱還原第二階段的動力學進行了分析,可以得出第二階段的平均活化能為362.16 kJ·mol–1,且該階段活化能為331.01~490.04 kJ·mol–1,變化較大,說明這一階段發生的反應較為復雜,且各反應之間的活化能差異明顯,二級化學反應是這一階段的主要控速環節,并確定了第二階段的主要控速方程。

     

    Abstract: The amount of zinc-containing EAF dust has increased due to the increased proportion of galvanized steel scrap used in the electric arc furnace (EAF) steelmaking process. If the zinc in the EAF dust is not recycled, it will not only lead to a waste of valuable metal resources but also results in environmental pollution. Zinc is mainly present in the EAF dust in the form of zinc ferrite (ZnFe2O4). Zinc ferrite is a kind of spinel mineral that exhibits a crystal lattice of greater stability, which increases the difficulty of recycling valuable elements such as zinc and iron from zinc-containing EAF dust. To further clarify the carbothermic reduction process of zinc ferrite, this paper studies the kinetics of the non-isothermal carbothermal reduction of zinc ferrite and its reduction reaction mechanism. The phase transition process of the zinc ferrite carbothermal reduction reaction was analyzed via the XRD results of the reduced zinc ferrite. FeO0.85·xZnO was found at 950 °C when Fe3+ was reduced to Fe2+. The relationship between the conversion and conversion rate of the zinc ferrite carbothermal reduction process is discussed. The reduction process can be divided into three stages, and the conversion of the second stage changes greatly (0.085–0.813). Finally, the kinetics of the second stage of the carbothermic reduction of the zinc ferrite at different heating rates was evaluated through the isoconversional method and the master curve fitting method. The activation energy of the second stage is between 331.01–490.04 kJ·mol?1, and the average activation energy is 362.16 kJ·mol?1. The large change in the activation energy in the second stage indicates that the reactions in this stage are more complicated, and there are obvious differences in the activation energy between the reactions. The secondary chemical reaction is the main rate-controlling link in the second stage, and the kinetics equation of the second stage is determined.

     

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