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硅鐵合金中金屬鈣元素對鋁脫氧鋼中夾雜物的影響

Effect of calcium in ferrosilicon alloys on inclusions in Al-killed steel

  • 摘要: 大尺寸CaO?Al2O3類夾雜物容易引起軸承鋼疲勞失效,大尺寸CaO?Al2O3類夾雜物的控制是生產高端GCr15軸承鋼的關鍵因素之一。精煉過程中合金引入雜質元素、渣精煉和精煉過程中卷渣是鋁脫氧軸承鋼中大尺寸CaO?Al2O3類夾雜物的主要潛在來源。硅鐵合金通常用來提高軸承鋼的淬火和抗回火軟化性。本文通過實驗室實驗、樣品分析和熱力學計算,研究了硅鐵合金中金屬鈣元素對鋁脫氧鋼中夾雜物的影響。硅鐵合金主要由深色的硅相和淺色的硅鐵相組成,鈣元素在硅相和硅鐵相的界面處以金屬化合物形式存在。研究發現,加入硅鐵合金后,鋼中總鈣(T.Ca)含量增加,鋼中的Al2O3和MgO·Al2O3夾雜物被改性為CaO?Al2O3類夾雜物,夾雜物尺寸隨著夾雜物中CaO含量增加而減小,鋼中并未生成大尺寸CaO?Al2O3類夾雜物。隨著鋼中T.Ca含量增加,夾雜物平均尺寸降低,鋼中T.O含量增加,表明硅鐵合金中金屬鈣元素不會直接引起鋼中大尺寸CaO?Al2O3類夾雜物的生成。但是生成的小尺寸固相CaO?Al2O3類夾雜物在水口處粘附結瘤,結瘤物脫落后會成為鋼中大尺寸CaO?Al2O3類夾雜物的來源之一。

     

    Abstract: Large CaO?Al2O3-type inclusions easily induce fatigue failure of bearing steels, so controlling large CaO?Al2O3-type inclusions is the key to producing high-quality GCr15-bearing steel. Impurity elements in alloys added during refining, slag refining, and slag entrainment during the refining process are the main potential sources for forming large CaO?Al2O3-type inclusions in Al-killed bearing steels. The ferrosilicon alloy is applied to improve the quenching and tempering softening resistance of Al-killed bearing steels. In this work, the effect of the calcium element in ferrosilicon alloys on inclusions in Al-killed bearing steel was studied through laboratory experiments, observations, and thermodynamic calculations. The ferrosilicon alloy mainly consists of the dark silicon and light ferrosilicon phases. The calcium element in ferrosilicon alloys exists as a metal compound at the interface between the silicon phase and the ferrosilicon phase. The total calcium (T.Ca) content in molten steel increases after adding the ferrosilicon alloy and modifying the Al2O3 and MgO·Al2O3 inclusions into CaO?Al2O3-type ones. The size of inclusions in the molten steel decreases with an increase in the CaO content in the inclusions. Large CaO?Al2O3-type inclusions are rarely generated. With the increase of the T.Ca in the molten steel, the T.O in the steel increases, whereas the average size of the inclusions decreases. It was observed that the calcium element in ferrosilicon alloys is not the direct cause for the formation of large size CaO?Al2O3 inclusions in the steel. However, the generated small, solid CaO?Al2O3-type inclusions clog the wall of the submerged entry nozzle, leading to dislodging of the big clogging lump into the molten steel. This lump is one of the reasons for large and irregularly shaped CaO?Al2O3 type inclusions in the steel product.

     

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