<th id="5nh9l"></th><strike id="5nh9l"></strike><th id="5nh9l"><noframes id="5nh9l"><th id="5nh9l"></th><strike id="5nh9l"></strike>
<progress id="5nh9l"><noframes id="5nh9l"><th id="5nh9l"><noframes id="5nh9l">
<th id="5nh9l"></th> <strike id="5nh9l"><noframes id="5nh9l"><span id="5nh9l"></span>
<progress id="5nh9l"><noframes id="5nh9l"><span id="5nh9l"><noframes id="5nh9l"><span id="5nh9l"></span><strike id="5nh9l"><noframes id="5nh9l"><strike id="5nh9l"></strike>
<span id="5nh9l"><noframes id="5nh9l">
<span id="5nh9l"><noframes id="5nh9l">
<span id="5nh9l"></span><span id="5nh9l"><video id="5nh9l"></video></span>
<th id="5nh9l"><noframes id="5nh9l"><th id="5nh9l"></th>
<progress id="5nh9l"><noframes id="5nh9l">

Ni55Mn25Ga18Ti2高溫形狀記憶合金的熱循環穩定性

Thermal cycling stability of Ni55Mn25Ga18Ti2 high-temperature shape memory alloy

  • 摘要: 選擇雙相韌化的Ni?Mn?Ga?Ti高溫形狀記憶合金為研究對象。制備了淬火態Ni55Mn25Ga18Ti2高溫形狀記憶合金,并對其在室溫至480 ℃之間進行高達500次的相變熱循環,獲得了5, 10, 50, 100和500次熱循環態樣品。采用X射線衍射、掃描電鏡、能譜儀、同步熱分析儀及室溫壓縮等實驗方法,研究了淬火態和熱循環態合金樣品的微觀組織、相變行為、力學及記憶性能,進而分析其熱循環穩定性。研究結果表明:經500次循環后,Ni55Mn25Ga18Ti2合金相結構和顯微組織未發生明顯變化,均為由非調制四方結構的板條馬氏體相和面心立方富Ni的γ相組成的雙相結構;隨著循環次數增加,馬氏體相變溫度幾乎不變,逆馬氏體相變溫度和相變滯后在循環5次后趨于穩定;抗壓強度及壓縮變形率波動幅度較小;形狀記憶性能下降,但形狀記憶應變仍保持在1.4%以上;Ni55Mn25Ga18Ti2高溫形狀記憶合金顯示出良好的熱循環穩定性。

     

    Abstract: Research on high-temperature shape memory alloys has attracted much attention due to the control requirements of the high-temperature drive (>100 ℃) and the overheating warning in high voltage transmissions, nuclear power, aerospace, automotive, oil exploration, and other engineering fields. High-temperature shape memory alloys refer to those with reverse martensitic transformation starting temperature (As) higher than 100 ℃. A wide range of high-temperature shape memory alloys exists, including Ti?Ni?Pd/Pt, Ni?Ti?Hf/Zr, Cu?Al?Ni, Ni?Mn?Ga, Ru-based, β-Ti-based, and Co-based systems. Besides the high transformation temperatures and good mechanical and shape memory properties, the thermal stability of microstructures and properties at high temperatures and after thermal cycling transformations is also an important basis for evaluating the practicability of high-temperature shape memory alloys. Dual-phase Ni?Mn?Ga?Ti high-temperature shape memory alloys were chosen because of their better ductility compared with single-phase Ni?Mn?Ga alloys. In this paper, the as-quenched Ni55Mn25Ga18Ti2 high-temperature shape memory alloy was prepared. Specimens are then thermal-cycled at a temperature between the room temperature and 480 ℃ for 5, 10, 50, 100, and 500 times. The thermal stability of the microstructure, martensitic transformation temperatures, and mechanical and shape memory properties were studied by X-ray diffraction analysis, scanning electron microscopy, simultaneous thermal analyzer, and room-temperature compression analysis. Results show that there are no obvious changes in the phase structure and microstructure of the Ni55Mn25Ga18Ti2 high-temperature shape memory alloy after 500 thermal cycles. All as-quenched and thermal-cycled specimens show dual-phase structures with non-modulated tetragonal martensite and Ni-rich face-centered-cubic γ phase. With the increase of thermal cycling times, the forward martensitic transformation temperatures are almost kept constant, and the reverse martensitic transformation temperatures and the hysteresis are observed to be steady when the thermal cycles exceed five times. After 500 thermal cycles, the compressive strength and compressive stain slightly change, and the shape memory strain drops but remains over 1.4%. The Ni55Mn25Ga18Ti2 high-temperature shape memory alloy shows high thermal cycling stability.

     

/

返回文章
返回
<th id="5nh9l"></th><strike id="5nh9l"></strike><th id="5nh9l"><noframes id="5nh9l"><th id="5nh9l"></th><strike id="5nh9l"></strike>
<progress id="5nh9l"><noframes id="5nh9l"><th id="5nh9l"><noframes id="5nh9l">
<th id="5nh9l"></th> <strike id="5nh9l"><noframes id="5nh9l"><span id="5nh9l"></span>
<progress id="5nh9l"><noframes id="5nh9l"><span id="5nh9l"><noframes id="5nh9l"><span id="5nh9l"></span><strike id="5nh9l"><noframes id="5nh9l"><strike id="5nh9l"></strike>
<span id="5nh9l"><noframes id="5nh9l">
<span id="5nh9l"><noframes id="5nh9l">
<span id="5nh9l"></span><span id="5nh9l"><video id="5nh9l"></video></span>
<th id="5nh9l"><noframes id="5nh9l"><th id="5nh9l"></th>
<progress id="5nh9l"><noframes id="5nh9l">
259luxu-164