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鞍山式貧赤鐵礦不同種類分選尾礦中鐵的賦存規律

Study of the occurrence law of iron in different types of sorting tailings of Anshan-type low-grade hematite

  • 摘要: 以齊大山鐵礦選礦分廠鐵尾礦為例,對重選尾礦、磁選尾礦、浮選尾礦和綜合尾礦4種不同種類尾礦的工藝礦物學性質進行對比分析,并對尾礦中鐵的可回收性進行評價。研究結果表明,尾礦中鐵礦物主要為赤鐵礦,脈石礦物主要是石英,有害元素S、P的含量低;尾礦中鐵的金屬分布率隨著粒級的變化,呈兩端高、中間低的規律。重選尾礦中鐵礦物主要包裹在粗顆粒脈石中,浮選尾礦中鐵礦物主要賦存在細顆粒連生體中,磁選尾礦中的鐵礦物粒度極細,綜合尾礦粒度范圍寬、粒度分布極不均勻。采用單一重選和磁選方法對不同種類尾礦進行再選,浮選尾礦指標最佳,重選尾礦次之,綜合尾礦最差,磁選尾礦屬于不可選。鞍山式貧赤鐵礦分選尾礦中鐵的賦存狀態決定了鐵的再回收潛力,可為此類分選尾礦的處理提供理論借鑒。

     

    Abstract: Anshan-type low-grade hematite ore is one of the most important types of iron ore in China. It is usually separated by a combined process of gravity concentration-magnetic separation-reverse flotation. However, the tailings produced by different separation operations have different properties, and a large amount of the residual iron in the minerals cannot be recovered effectively; therefore, mixing these tailings is unscientific for most concentrators. Given this situation, this paper takes the iron tailings of the Qidashan iron ore dressing plant as an example to make a comparative analysis of the technological mineralogy of four types of tailings (i.e., gravity tailings, magnetic tailings, flotation tailings, and mixed tailings) and evaluate the recoverability of iron in these tailings. The results show that the main iron and gangue minerals are hematite and quartz, respectively. The content of harmful elements S and P is low in the tailings. In addition, the metal distribution rate of iron in the tailings varies with the size, showing a rule of high at both ends and low in the middle. It is also found that iron minerals are mainly wrapped in coarse gangue, and iron minerals in the flotation tailings are mainly contained in fine-grained conglomerates. Although the iron minerals in the magnetic separation tailings are extremely fine, mixed tailings have a wide range of particle sizes and extremely uneven distribution. Single gravity separation and magnetic separation methods are used to reconcentrate different types of tailings, and the best index is found to exist in flotation tailings, followed by gravity tailings, and that of mixed tailings is the worst. However, recovering iron from magnetic tailings is pointless. The mineralogical characteristics of Anshan-type hematite ore tailing underlies its recovery potential of iron and provides a reference for the retreatment of similar iron ore tailings.

     

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