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鈣處理對20CrMnTiH齒輪鋼中非金屬夾雜物的影響

Effect of calcium treatment on nonmetallic inclusions in 20CrMnTiH gear steel

  • 摘要: 鋁脫氧齒輪鋼中易生成大量的高熔點Al2O3類夾雜物,容易導致水口結瘤及鋼材性能惡化,目前較常采用鈣處理將鋼中高熔點的Al2O3類夾雜物改性為低熔點的鈣鋁酸鹽類夾雜物。合理的鈣處理可以減輕水口結瘤并提高連鑄過程鋼液的可澆性,工業試驗研究了喂鈣前鋼液中T.Ca含量、喂鈣速度、喂鈣量、凈空高度及渣厚等參數對齒輪鋼中鈣收得率的影響,并在1.5 m·s?1的喂鈣速度條件下研究了不同喂鈣量對鈣處理過程中齒輪鋼中非金屬夾雜物改性的影響。研究結果表明,當喂鈣前鋼液中T.Ca的質量分數小于10×10?6,喂鈣速度為1.5 m·s?1,適當降低喂鈣量和凈空高度和渣厚,鋼液中鈣收得率均高于20%。當鋼液中T.Ca的質量分數高于17×10?6時,鋼中生成大量高熔點CaS型夾雜物,三元相圖中夾雜物的平均質量分數遠離液相區。隨著齒輪鋼中T.Ca含量的增加,夾雜物的平均尺寸和數密度逐漸增加。熱力學計算結果與工業試驗鈣處理對鋼中非金屬夾雜物改性效果具有較好的一致性。

     

    Abstract: Obtaining high-quality gear steel calls for strict requirements on the oxygen content, shape, composition, size, and distribution of nonmetallic inclusions to ensure high-quality steel and castability of the molten steel during the continuous casting process. Al2O3 inclusions with high melting point are easily generated in Al-deoxidized gear steel, and they easily result in nozzle clogging and deterioration in the properties of the steel. A reasonable calcium treatment can reduce the nozzle clogging and increase improving the castability of the molten steel, and thus it has been widely used in steel plants. Calcium treatment is often used to convert Al2O3 inclusions with high melting point to calcium aluminate with low melting point. The factors of calcium treatment on nonmetallic inclusions in gear steel were investigated through industrial trials. The dependency of calcium yield on various factors, namely, the amount of calcium addition, feeding speed of calcium wire, and feeding position and slag thickness were discussed. The effect of the amount of calcium addition on nonmetallic inclusions in the molten steel was studied at a feeding rate of 1.5 m·s?1. With the initial mass fraction of T.Ca lower than 10×10?6 in the steel and a feeding rate of 1.5 m·s?1, the calcium yield can be higher than 20% if the amount of calcium addition, clearance height, and slag thickness during the refining process are appropriate. Large numbers of nonmetallic CaS inclusions with high melting point are formed in the molten steel with the mass fraction of T.Ca higher than 17×10?6, and the inclusions are formed far away from the liquidus region. With increase in the T.Ca content in the steel, the average size and number density of the nonmetallic inclusions gradually increase. The effect of calcium treatment on the modification of nonmetallic inclusions studied by thermodynamic calculation results agrees well with the measurements taken via industrial trials.

     

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