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典型鐵合金渣的資源化綜合利用研究現狀與發展趨勢

Review of comprehensive utilization of typical ferroalloy slags

  • 摘要: 典型鐵合金渣(硅錳渣,鎳鐵渣,鉻鐵渣)面臨產量大、利用率低等緊迫問題。目前,我國對鐵合金渣的利用主要集中于水泥、混凝土等傳統建筑材料,但是其能耗大和產品價值相對局限。隨著市場需求以及環保能源意識的提高,對鐵合金渣的綜合利用不斷從傳統建筑材料向具有低能耗、高附價值的新型材料方向轉型。本文簡要介紹了這三種典型鐵合金渣的來源及其分類情況,系統分析了它們的化學成分及其礦物組成的差異性,重點概述了它們在水泥、混凝土等傳統建筑材料,以及在地質聚合物、無機礦物纖維、微晶玻璃、人造輕骨料、耐火材料、新型墻體材料、特色功能陶瓷等新型材料領域應用的國內外最新研究進展,分類總結不同種類鐵合金渣應用于不同材料的優缺點,并對其今后的利用方向與途徑提出了展望,指出了要進一步研究并突破主要利用方式的限制瓶頸、制定并完善相關應用及污染控制標準、以及深入開發并推廣高附加值產品的重點發展方向。

     

    Abstract: Three typical ferroalloy slags, namely, silicon–manganese, nickel–iron, and chrome–iron slags, are produced in large quantities as by-products. This is because they are not efficiently utilized, which creates lots of pressure on environmental capacity and development of enterprises. At present, comprehensive utilization of ferroalloy slags is mainly concentrated on the traditional building materials such as cement and concrete. Although the construction industry consumes a large amount of ferroalloy slags, their high-energy consumption and relatively limited product value limit their maximum utilization. With the increasing market demand and improvement of energy and environmental awareness, the research on rational utilization of ferroalloy slags has been changing from its use as raw materials in traditional building materials to use as raw materials to produce new products with comparatively lower energy consumption and higher product value, which explores the possibility of slag reutilization in other fields. Based on the quality requirements of different ferroalloys, there are significant differences in the requirements of the raw materials and different smelting processes. As a result, different types of ferroalloy slags, having different physical and chemical properties, are produced. This study briefly presented the uses of the silicon–manganese, nickel–iron, and chrome–iron slags. It also showed how to classify these three typical ferroalloy slags. The differences of their chemical and mineral phase composition were also systematically analyzed in this study, which discussed different properties of different slags and provided the basic theoretical guidelines on how to efficiently utilize these slags. This study also emphatically summarized the latest domestic and foreign research advancements about their utilization in traditional building materials such as cement and concrete, and in new functional materials such as geopolymer, inorganic mineral fiber, microcrystalline glass, artificial light aggregate, and refractory materials required to build walls and as alternative raw materials to prepare functional ceramics. Based on the results of this study, we summarized the advantages and disadvantages of using the abovementioned ferroalloy slags as raw materials to generate different materials, and put forward the prospects for its future utilization direction and approach. The study also guided the key development areas for further studying and breaking through the bottleneck of the main utilization mode, formulating and improving the relevant application and pollution control standards, and developing and promoting high value-added products.

     

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