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室溫注氫Fe-Cr合金在不同溫度退火后位錯環的表征

Characterization of dislocation loops in hydrogen ion-implanted Fe-Cr alloy annealed at different temperatures

  • 摘要: 利用透射電子顯微鏡, 通過構建位錯環在不同晶帶軸下的投影圖結合位錯環消光判據, 對室溫注氫后Fe-9%Cr模型合金在400、500及550℃退火形成的1/2 〈111〉和〈100〉兩種類型的位錯環進行了表征. 實驗結果表明, 室溫注氫Fe-9%Cr合金中柏氏矢量為〈100〉型位錯環的數量隨著退火溫度的升高而逐漸增加. 在400和500℃退火后, 〈100〉型位錯環所占比例分別為16.48%、92.78%;當退火溫度升高到550℃時, 位錯環全部轉變為〈100〉型位錯環. Fe-9%Cr合金中位錯環類型轉變溫度區間為400~500℃, 與純鐵相比, 添加Cr元素能夠使位錯環類型轉變溫度升高.

     

    Abstract: Reduced-activation ferritic/martensitic (RAFM) steels, based on Fe-Cr alloys, have been considered to be one of the most promising candidate structural materials for future fusion reactors. Dislocation loops, as one of the most common microstructures induced by radiation, are the key factors in the deterioration of material properties. Dislocation loops with different Burgers vectors have different effects on material properties. Currently, a consensus exists suggesting that there are two kinds of dislocation loops with Burgers vectors of 1/2 〈111〉 and 〈100〉 in bcc iron-based alloys. In this study, the Burgers vectors of dislocation loops formed at the annealing temperatures of 400, 500, and 550℃ in hydrogen-ion implanted Fe-9%Cr model alloy were examined based on dislocation loop maps and dislocation loop invisibility criteria. Dislocation loop maps manifest such that under the 〈100〉 or 〈110〉 zone axes, it is easy to distinguish 1/2 〈111〉 and 〈100〉 edge dislocation loops, while under the 〈111〉 zone axis, the loops cannot be distinguished. By direct comparison between loop maps and loop images obtained through transmission electron microscope (TEM), the dislocation loops with Burgers vectors of 1/2 〈111〉 and 〈100〉, formed at different annealing temperatures, were characterized. The results of the characterization show that with increasing annealing temperature, the size of the dislocation loops increases while density decreases. Furthermore, the proportion of dislocation loops with a Burgers vector of 〈100〉 increases with rising temperature. After annealing at 400℃ and 500℃, the percentages of 〈100〉 type dislocation loops are 16.48% and 92.78% respectively, in hydrogen-ion implanted Fe-9%Cr alloy. While the temperature is raised to 550℃, all the dislocation loops are of 〈100〉 type loops. This indicates that the transition temperature range of dislocation loops in Fe-9%Cr is 400℃-500℃. Compared with pure iron, the presence of Cr element promotes the transition temperature of dislocation loops from 1/2 〈111〉 type to 〈100〉 type.

     

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