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多孔基定形復合相變材料傳熱性能提升研究進展

Thermal conductivity enhancement of porous shape-stabilized composite phase change materials for thermal energy storage applications: a review

  • 摘要: 先進的相變儲能材料是推動儲能技術發展的核心和關鍵,在促進新能源開發和提高能源利用率中起著至關重要的作用。因在相變過程中具有高儲能密度和小體積變化等優勢,相變材料中應用最多的是固?液相變材料。然而在其相變過程中會發生固態向液態的轉變,為了避免其在液相狀態下的泄露,需要加以定形才能使用。多孔基復合相變材料在有效防止固液相變發生泄露的同時,還需兼顧定形復合相變材料傳熱性能的提升。本文針對這個問題進行了大量的調研,對近年來國內外在提高多孔基定形復合相變材料傳熱性能方面的研究進行了綜合分析,介紹了三種強化傳熱的方法,分別是使用高導熱多孔材料做載體材料、摻雜高導熱納米材料做添加劑以及構筑高導熱多級結構多孔材料,并對提升復合相變材料傳熱性能研究方法的前景作了展望。

     

    Abstract: How to realize the efficient use of the renewable energy sources is a present-day challenge to the technologists and has become an important issue in their large scale applications. Energy storage not only reduces the mismatch between supply and demand but also improves the performance and reliability of energy systems and plays an important role in conserving the energy. Current energy storage techniques mainly include sensible heat storage, latent heat storage and chemical reaction heat storage. The researchers place emphasis on the latent heat storage due to its advantages of high heat storage density, little temperature fluctuation and easily controllable utility system. In principle, phase change materials (PCMs) are used for the latent heat storage to absorb and release large amounts of latent heat during their phase change process. Therefore, PCMs are the key factor for the development of latent energy storage technology and play the crucial role in exploring new energy and improving energy utilization. The solid-liquid transition is more efficient compared with the other transformations due to its high latent heat density and small volume change. However, the leakage of solid-liquid PCMs above the melting point from the thermal storage system still hinders their practical applications. Considerable efforts have been devoted to introducing the porous support and development of shape-stabilized composite PCMs to address this technical issue. During the melting or solidifying processes, the PCMs store or release latent heat, while the support materials confine the melted phase from leaking and keep the whole system in the solid state. Moreover, low thermal conductivity of PCMs may degrade the performance for energy storage and thermal regulation during the melting and freezing cycles and restrict their final applications. Therefore, the necessity to enhance thermal conductivity of porous shape-stabilized composite PCMs is evident. In this paper, the recent researches on the enhancement of conductivity of porous shape-stabilized composite PCMs were reviewed. We studied the thermal conductivity enhancement techniques, which included impregnation of PCMs into porous materials with high thermal conductivity, introducing of high conductivity nano-materials and porous support materials into PCMs, construction of hybrid composite for shape stabilized phase change materials. The evaluation of each thermal conductivity enhancement technique was discussed. Finally, we had provided a brief outlook and future challenges in enhancing thermal conductivity of porous shape-stabilized composite PCMs.

     

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