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特殊鋼鋼渣用作橡膠功能填料及其安全性分析

Safety analysis of specialty-steel slag used as rubber functional filler

  • 摘要: 以特殊鋼鋼渣、炭黑、促進劑、硫磺、氧化鋅、硬脂酸與復合橡膠制備特殊鋼鋼渣基復合橡膠。測試了內輻射指數、外輻射指數、安定性、拉伸強度、撕裂強度、拉斷伸長率、邵爾A硬度、極限氧指數、燃盡時間、浸出液中重金屬濃度、礦物組成、粒徑分布、導熱系數、孔結構、化學成分、微觀形貌和熱穩定性。研究了特殊鋼鋼渣作為橡膠功能填料的可行性與環境風險。結果表明:特殊鋼鋼渣的礦物組成為Ca2SiO4、Ca3Al6Si2O16、(Fe, Mn)2SiO4、Ca3Al2(SiO43、Na2TiSiO5、CuMn6SiO12、Na2SiO5、Pb3Ta2O8、Pb3SiO7等金屬固熔體,特殊鋼鋼渣具有良好的粒徑分布,其安全性與安定性滿足相關國標的要求。特殊鋼鋼渣基復合橡膠中特殊鋼鋼渣摻量為20%~40%時,特殊鋼鋼渣基復合橡膠的拉伸強度為20.0~21.5 MPa、撕裂強度為45.2~48.6 kN·m?1、拉斷伸長率為475%~501%、邵爾A硬度為63.5~65.3、極限氧指數為18.5~18.6、燃盡時間為264~292 s、導熱系數為0.15~0.17 W·m?1·K?1。特殊鋼鋼渣的主要重金屬氧化物為Cr2O3、PbO和CuO,且以穩定的金屬固熔體存在,特殊鋼鋼渣基復合橡膠中Cu、Zn、Cd、Pb、Cr、Ba、Ni、As等重金屬浸出濃度遠低于危險廢物鑒別標準限值,因此將特殊鋼鋼渣作為橡膠功能填料安全、可行。

     

    Abstract: The utilization of high-value-added metallurgical solid waste, such as the use of an inexpensive specialty-steel slag as a rubber functional filler, is an important sustainable development strategy. In this study, we prepared specialty-steel slag-based rubber composites from specialty-steel slag, carbon black, an accelerator, sulfur, zinc oxide, stearic acid, and compound rubber. Then we conducted tests to determine the internal exposure index, external exposure index, stability, tensile strength, tear strength, elongation at break, shore A hardness, limiting oxygen index, burnout time, leaching concentration of heavy metals, mineral composition, particle size distribution, heat conductivity coefficient, pore structure, chemical composition, microstructure, and thermal stability of the composites. We also studied the feasibility and environmental risk associated with using specialty-steel slag as a rubber functional filler. The results show that the mineral composition of the specialty-steel slag includes Ca2SiO4, Ca3Al6Si2O16, (Fe, Mn)2SiO4, Ca3Al2(SiO4)3, Na2TiSiO5, CuMn6SiO12, Na2SiO5, Pb3Ta2O8, Pb3SiO7, and other solid metal melts. This slag also has a good particle size distribution, and its safety and stability meet the requirements of relevant national standards. When the content of the specialty-steel slag in specialty-steel slag-based rubber composites ranges between 20%–40%, these composites have a tensile strength ranging from 20.0–21.5 MPa, a tear strength of 45.2–48.6 kN·m?1, an elongation at break value of 475%–501%, a shore A hardness of 63.5–65.3, a limiting oxygen index of 18.5–18.6, a burnout time of 264–292 s, and a heat conductivity coefficient of 0.15–0.17 W·m?1·K?1. The main heavy-metal oxides in the specialty-steel slag are identified as Cr2O3, PbO, and CuO, which mainly exist as stable solid metals. In addition, the leaching concentration of the heavy metals, such as Cu, Zn, Cd, Pb, Cr, Ba, Ni, and As, from the specialty-steel slag-based rubber composites is much lower than the limit value of the hazardous-waste identification standards. Therefore, specialty-steel slag is safe and feasible for use as a rubber functional filler.

     

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