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稀土-鎂復合處理對GCr15軸承鋼中夾雜物的影響

Effect of rare earth and magnesium complex treatment on inclusions in GCr15 bearing steel

  • 摘要: 為了盡可能的去除鋼中大顆粒的夾雜物, 在實驗條件下通過向GCr15軸承鋼中添加適量鎂、稀土對夾雜物進行改性, 并利用Aspex夾雜物自動分析儀和掃描電鏡對鋼中改性后的夾雜物尺寸、類型、形貌等進行了觀察、分析, 研究了稀土-鎂復合處理對夾雜物的影響規律.研究結果表明, 對軸承鋼中加入微量鎂處理, 可將未進行鎂處理鋼中的MnS-Al2O3、MnS、Al2O3夾雜改性為以含硫、鎂復合夾雜物為主, 同時包含少量Al2O3、鎂鋁尖晶石夾雜.進一步采用稀土-鎂復合處理后, 鋼中的夾雜物轉變為主要以含Re-S-O夾雜物為主, Al2O3、MnS、鎂鋁尖晶石夾雜逐步消失, 且夾雜物成球狀分布, 絕大多數夾雜物在5 μm以下.稀土-鎂復合處理軸承鋼后, 10 μm以上的大顆粒夾雜物大大降低, 鋼中的夾雜物明顯得到細化.鋼中鎂含量不變時, 隨著稀土含量的增加, 大顆粒夾雜物比例明顯下降.而在稀土含量相近的情況下, 增加鋼中的鎂含量也有利于大顆粒夾雜物的去除.稀土-鎂的相互作用進一步促進了夾雜物的細化.

     

    Abstract: Bearing steel has very strict requirements on the size, shape, and quantity of non-metallic inclusions. Even if the total oxygen content in steel is kept at very low levels, large inclusions are not completely removed. These large inclusions have a decisive effect on the fatigue life of bearing steel. To remove the large inclusions in the bearing steel as much as possible, the effect of rare earth and magnesium duplex treatment on inclusions in GCr15 bearing steel was investigated by adding moderate rare earth and magnesium to liquid steel under experimental conditions. The size, composition, and morphology of the inclusions were observed by combining Aspex inclusion automatic analysis technology and scanning electron microscope. The experimental results show that the inclusions in steel before modification are mainly composed of MnS-Al2O3, MnS, and Al2O3, and the inclusions are modified to be composed of a large number of compound inclusions containing sulfur and magnesium and a small amount of Al2O3 and magnesia alumina spinel after adding trace magnesium to steel. After complex treatment by rare earth and magnesium, the inclusions are mainly composed of Re-O-S. Al2O3, MnS, and magnesia alumina spinel vanish gradually. The inclusions are spherically distributed, and most of them have diameter less than 5 μm. Inclusions with diameters greater than 10 μm are greatly reduced. Thus, the inclusions in GCr15 bearing steel are obviously refined after rare earth and magnesium complex treatment. When the magnesium content in the steel remains unchanged, the proportion of large particle inclusions decreases with increasing content of rare earth. When the content of rare earth is similar, increasing the magnesium content in steel is beneficial to the removal of large particle inclusions. The interaction of rare earth and magnesium further promotes the refinement of inclusions.

     

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